I How do point charges in a conductor move and stop?

Click For Summary
In classical contexts, point charges in conductors cannot be accurately described using Newtonian mechanics, as charge transport is fundamentally a quantum mechanical process. While semi-classical models like the Drude model exist, they fail to account for individual charge behavior and lead to paradoxes when using Dirac delta functions as sources in Maxwell's equations. Charges near a conductor's boundary do not "hit" the surface but respond to an internal electric field created by surface charge density, preventing perpendicular current flow. The work function and surface charge interactions maintain charge stability at the surface, while quantum mechanics provides a more accurate framework for understanding these phenomena. Ultimately, classical models are insufficient for explaining the behavior of electrons in conductors.
  • #31
sophiecentaur said:
Work Function?
that's not a kind of energy
 
  • Skeptical
Likes davenn
Physics news on Phys.org
  • #32
feynman1 said:
that's not a kind of energy
Yes it is, it is the minimum amount of energy needed to move an electron from a solid to the vacuum,
 
  • #33
f95toli said:
Yes it is, it is the minimum amount of energy needed to move an electron from a solid to the vacuum,
Yes, sorry I didn't mean to deny it being an energy. I just meant that wasn't 'work' in the usual sense of introductory physics.
 
  • Skeptical
Likes Motore
  • #34
feynman1 said:
Yes, sorry I didn't mean to deny it being an energy. I just meant that wasn't 'work' in the usual sense of introductory physics.
The clue is surely in the Units involved, rather than a "sense". In the case of Work Function, the name itself associates the Kinetic Energy and the Photon Energy so it's actually quite hard to be confused in the context of Photoelectricity. What we are discussing is not exactly introductory Physics.
 
  • Like
Likes Motore
  • #35
What kind of model are those point charges on physics textbooks? Are they valence electrons or ions? If those point charges can move, can they not be ions?
 
  • #36
Only in a fluid.
 
  • #37
sophiecentaur said:
Only in a fluid.
can't get what you mean
 
  • Like
Likes vanhees71 and Delta2
  • #38
feynman1 said:
can't get what you mean
In a solid, the ions are locked in place; in a fluid they can move.
 
  • Like
Likes feynman1
  • #39
sophiecentaur said:
In a solid, the ions are locked in place; in a fluid they can move.
Very well! In a physics textbook with point charges (+ and -), should we always regard + to be ions and - to be electrons? Then if the context is a solid, + point charges can't move, but there's no such restriction on physics textbooks, why?
 
  • #40
feynman1 said:
Very well! In a physics textbook with point charges (+ and -), should we always regard + to be ions and - to be electrons? Then if the context is a solid, + point charges can't move, but there's no such restriction on physics textbooks, why?
The Physics books that I have read all tell us that charge is carried in metals (and other solids) by negative charges (electrons). Can you find anywhere that the "restriction" is relaxed? By definition, if the positive ion cores in solids could move then why wouldn't the 'solid' flow and be a liquid? Or are you just trying to wind me up?

PS If you consider the +holes in a semiconductor to be charge carriers, they only exist because of the motion of electrons from atom and the + ions do not actually move; holes are just a way of thinking about it.
 
  • Like
Likes vanhees71
  • #41
sophiecentaur said:
The Physics books that I have read all tell us that charge is carried in metals (and other solids) by negative charges (electrons). Can you find anywhere that the "restriction" is relaxed? By definition, if the positive ion cores in solids could move then why wouldn't the 'solid' flow and be a liquid? Or are you just trying to wind me up?
A pair of + and + charges could be initially in the interior of a metal. Afterwards both charges will be repelled and move in the metal. If this appears in a textbook, that'll look quite normal and none doubts about whether + charges are supposed to move?
 
  • #42
feynman1 said:
If this appears in a textbook,
I challenge you to find this idea in a textbook. Ions (+ and -) are held in place in a solid and that is what defines the solid phase. If they could move around then would the solid be solid? In a solution (e.g. water) the theory describes the simple situation of a Salt (NaCl) Solution as mobile Na+ and Cl- having been separated from each other (in their solid state).

Taking this one stage further, it does happen that impurity ions can slowly make their way below the surface of a 'pure' solid material but, unless the substance is near its melting point, the time scale is many years. Alloys can form on the surface of metals when a melted solder (+ metal ions) can penetrate the faces of two copper wires and form a bond. But I would say that none of this is regarded as a flow of electric current.
 
  • Like
Likes vanhees71
  • #43
sophiecentaur said:
I challenge you to find this idea in a textbook.
Do you mean this pic in a textbook can only be correct if it implies that this happens in a fluid or free space?
1626001472676.png
 
  • #45
I read the picture as describing the magnetic part of the Lorentz force on a positively charged point particle. That holds in free space as well as in the medium. In the latter case, of course, there are other forces by interaction with the medium, which can be described macroscopically by friction. The relevant transport coefficient is electric conductivity.

In a usual metallic conductor, what's moving are the conduction electrons which are quasifreely moving quasiparticles.

In semiconductors the charge carriers can be either negatively or positively charged quasiparticles, depending on the doping of the material. The positively charged quasiparticles are microscopically "holes", i.e., unoccupied electron states.

Which electric charge the relevant quasiparticles make up a current within a solid can be measured by making use of the Hall effect, which is based on the above pictured force of a charged particle in a magnetic field.
 
  • Like
  • Informative
Likes sophiecentaur, Delta2 and Lord Jestocost
  • #46
Learning by telling never works as well as learning by reading and listening.
 
  • Like
Likes Vanadium 50 and jbriggs444
  • #47
Does electrostatic equilibrium in a metal mean that electrons don't move at all or they do move but their electric effects like electric field remain constant in some sense?
 
  • #48
From non Newtonian mechanics, what will happen to electrons when they hit a conductor wall?
 
  • #49
feynman1 said:
what will happen to electrons when they hit a conductor wall

You are (still) describing a classical path. Electrons behave quantum-mechanically, not classically.
 
  • Like
Likes vanhees71
  • #50
Vanadium 50 said:
You are (still) describing a classical path. Electrons behave quantum-mechanically, not classically.
What's the correct way of describing this without using 'hit'?
 
  • #51
feynman1 said:
What's the correct way of describing this without using 'hit'?
Did you look at the link to the wiki about Friedel oscillations?
A defect and a surface is not exactly the same thing, but both will break the periodicity of the lattice. The Friedel oscillation model should give you some idea of how this works.
 
  • Like
Likes vanhees71
  • #52
f95toli said:
Did you look at the link to the wiki about Friedel oscillations?
A defect and a surface is not exactly the same thing, but both will break the periodicity of the lattice. The Friedel oscillation model should give you some idea of how this works.
Thanks for the suggestion. I did, but don't get what it implies. Could you give any qualitative result?
 
  • Like
Likes Delta2
  • #53
feynman1 said:
Thanks for the suggestion. I did, but don't get what it implies. Could you give any qualitative result?
I am not sure that would help since I would just be repeating what is on the wiki page. Do you understand the bit about describing the electrons using a plane wave-like wavefunction with a specific Fermi wave vector?

If not, you need to start by reading more about solid state physics. There is now way you can understand what happens at a surface unless you have some idea of what happens inside a solid.
 
  • Like
Likes Vanadium 50
  • #54
f95toli said:
I am not sure that would help since I would just be repeating what is on the wiki page. Do you understand the bit about describing the electrons using a plane wave-like wavefunction with a specific Fermi wave vector?

If not, you need to start by reading more about solid state physics. There is now way you can understand what happens at a surface unless you have some idea of what happens inside a solid.
Thank you. Not knowing much about solid state, so looking for a layman's/Newtonian description.
 
  • #55
feynman1 said:
Thank you. Not knowing much about solid state, so looking for a layman's/Newtonian description.
Newtonian mechanics is not of much use in solid state systems.
Since the electrons in the case of Friedel oscillations (and in many other cases) are described as plane waves you will find that wave mechanics (interference/diffraction) is more relevant if you insist on using some parts of classical physics. However, that still won't help you e.g. explain scattering between different k-states.
 
  • Like
Likes vanhees71
  • #56
f95toli said:
Newtonian mechanics is not of much use in solid state systems.
Since the electrons in the case of Friedel oscillations (and in many other cases) are described as plane waves you will find that wave mechanics (interference/diffraction) is more relevant if you insist on using some parts of classical physics. However, that still won't help you e.g. explain scattering between different k-states.
What happens to the wave probability function of an electron when getting close to the boundary?
 
  • #58
feynman1 said:
What happens to the wave probability function of an electron when getting close to the boundary?
Is it likely or unlikely to appear outside the surface? There's a clue about the probability function at points near the 'boundary'. That's really a tautology because that is what defines a boundary.
 
  • #59
berkeman said:
Take 1D. An electron is put in a 1D conductor with a potential V=0 -1<x<1 and very high elsewhere. Schrodinger's solution suggests the prob distribution on the well boundaries -1 and 1 is the least (and 0 for an infinite well). Why does this result contradict charges staying on the boundary of a conductor?
 
  • #60
feynman1 said:
Why does this result contradict charges staying on the boundary of a conductor?
The probability distribution has to go to zero at some stage, past a notional boundary. Any model must include this, surely?
 

Similar threads

Replies
17
Views
2K
Replies
36
Views
3K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 14 ·
Replies
14
Views
3K
Replies
7
Views
2K
  • · Replies 27 ·
Replies
27
Views
3K
Replies
4
Views
1K
  • · Replies 16 ·
Replies
16
Views
5K
  • · Replies 19 ·
Replies
19
Views
1K
  • · Replies 5 ·
Replies
5
Views
856