How Do You Calculate Iron Concentration in Tablets from AAS Data?

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SUMMARY

The discussion focuses on calculating the concentration of iron in tablets using Atomic Absorption Spectroscopy (AAS) data. Three brands of iron tablets were analyzed, with Sample A showing an absorbance of 0.85 and a concentration of 4.7 ppm, while Sample B had an absorbance of 0.8 and a concentration of 0.6 ppm. The methodology involved dissolving the tablets in hydrochloric acid and measuring the absorbance after dilution to a final volume of 250 mL. The key to calculating the concentration of iron in the tablets lies in understanding the relationship between absorbance, concentration, and the volume of the solution.

PREREQUISITES
  • Atomic Absorption Spectroscopy (AAS) fundamentals
  • Understanding of molarity and concentration calculations
  • Knowledge of parts per million (ppm) and its equivalence to milligrams per liter
  • Familiarity with the periodic table for atomic weights
NEXT STEPS
  • Learn how to perform AAS calibration and standardization
  • Research the calculation of concentration from absorbance using Beer-Lambert Law
  • Explore the preparation of solutions for spectroscopic analysis
  • Study the significance of atomic weights in chemical calculations
USEFUL FOR

Chemistry students, laboratory technicians, and professionals involved in pharmaceutical analysis or quality control of dietary supplements.

ASidd
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A group of students decided to use AAS to analyze three different brands of iron tablets to determine their content. They placed a tablet in a 100 mL beaker with 6 mol/L HCl and covered it with a watch glass and heated slowly for 15 min. They then filtered the solution into a 250 mL volumetric flask and topped it up to mark with distilled water.

They determined the absorbance of the sample and repeated the same process for the other two samples

Sample A: Absrobance =0.85 concentration of iron in solution = 4.7 ppm
Sample B Absorbance = 0.8 Concentration of iron in solution = 0.6 ppm

Calculate the concentration of iron in the tablet itself.

Homework Equations



Equations:
Molarity = n/v

The Attempt at a Solution


I have no clue what to do. If only somebody can point me in the right direction I would be very grateful.
 
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Obviously sample A and sample B are either of different brands or of different product editions. Helpful fact to know is that parts per million (abbreviated, "ppm") is nearly the same as milligrams per liter. You already know that the solutions prepared for each sample are 250 ml. each. You need to know the atomic weight of iron, which you can find in common reference works such as Periodic Table. You are interested in amount of iron in each tablet.

n/v ... How many moles of iron in how much volume of solution? Each 250 ml. solution contains the iron from the tablet sample.
 

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