How Do You Determine the Correct Wave Function in a Quantum Square Well?

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SUMMARY

The discussion focuses on determining the correct wave function for a free particle in an infinite potential square well, specifically between -L/2 and L/2. The general solution derived from the time-independent Schrödinger equation is ψ=Acos(kx) + Bsin(kx). The participants clarify that assuming A=0 leads to ψ=Bsin(2n∏x/L), while assuming B=0 results in ψ=Acos([2n+1]∏x/L). Both solutions are valid under different boundary conditions, and the wave function must be normalized within the specified range due to the infinite potential walls.

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  • Understanding of the time-independent Schrödinger equation
  • Knowledge of boundary conditions in quantum mechanics
  • Familiarity with trigonometric identities and their applications in wave functions
  • Concept of normalization of wave functions in quantum mechanics
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serverxeon
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Homework Statement



Assume a free particle, V=0, in a infinite potential square well between -L/2 and L/2
solve for the wave function for this particle.

Homework Equations



Time independent Schrödinger equation

The Attempt at a Solution



After arriving at the second order differential equation, I get a general solution of
ψ=Acos(kx) + Bsin(kx)

How do I go on to solve for A, B and k?

I've plugged in the boundary conditions, but the solution is still quite indeterminate.

I have to assume A=0, then ψ=Bsin(2n∏x/L)
however, if I assume B=0, I get ψ=Acos([2n+1]∏x/L)

which is correct?
I do need to pick one before going onto normalising right?
 
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serverxeon said:
I've plugged in the boundary conditions, but the solution is still quite indeterminate.

I have to assume A=0, then ψ=Bsin(2n∏x/L)
however, if I assume B=0, I get ψ=Acos([2n+1]∏x/L)

which is correct?
Can you find a trigonometric relation between these two solutions?
 
You can rewrite the solution to ψ=Aexp(ik)+Bexp(-ik) (k=2pi/λ)

when x→+∞,ψ=0.so A=0.
when x→-∞,ψ=0, so B=0

that means ψ is a segmented function.

your solution is right,and hope my answer can help you to comprenhen it in other way.
 
er, nope.
some pointers pls?
 
YOUGI said:
You can rewrite the solution to ψ=Aexp(ik)+Bexp(-ik) (k=2pi/λ)

when x→+∞,ψ=0.so A=0.
when x→-∞,ψ=0, so B=0
The wave function is limited to the range -L/2, L/2 because of the infinite wall.
 
serverxeon said:
er, nope.
some pointers pls?
$$\cos(x + \pi/2) = -\sin(x)$$
Your two solutions are the same
 

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