How do you know if a reaction will take place or not

  • Thread starter Thread starter usermanual
  • Start date Start date
  • Tags Tags
    Reaction
Click For Summary
SUMMARY

This discussion focuses on determining whether a chemical reaction will occur, specifically addressing single and double displacement reactions. The activity series is crucial for single displacement reactions, such as the reaction between zinc and hydrochloric acid (Zn + 2HCl -> ZnCl2 + H2). For double displacement reactions, like the interaction of sodium sulfide (Na2S) with water, thermodynamics and kinetics are essential factors. The discussion highlights that Na2S dissociates in water to form sodium ions and hydrosulfide ions, demonstrating that not all combinations of reactants will result in a reaction.

PREREQUISITES
  • Understanding of the activity series in chemistry
  • Knowledge of thermodynamics and reaction energetics
  • Familiarity with reaction kinetics and rate measurements
  • Basic concepts of acid/base reactions and pKa values
NEXT STEPS
  • Study the activity series for predicting single displacement reactions
  • Learn about thermodynamic principles, including Gibbs free energy calculations
  • Explore reaction kinetics and methods for measuring reaction rates
  • Investigate acid/base chemistry, focusing on pKa values and their implications
USEFUL FOR

Chemistry students, particularly those in high school or introductory college courses, educators teaching chemical reaction principles, and anyone interested in understanding the fundamentals of reaction predictability.

usermanual
Messages
9
Reaction score
0
how do you know if a reaction will take place or not
like i know that i have to use the activity series and all but isn't that only when the reaction thing is single displacement where there 1 element in the first thing and then 2 element in the second compound so like this (a+ bc= ac + b) so for example Zn(s) + 2HCl(aq) -> ZnCl2(aq) + H2(g) so this reaction occurs because Zn is more to the left of the activity series compared to H but my question is what if its a double displacement reaction so AB+ CD -> CB + AD
for example i have Na2S + H2O how would i kno if a reaction takes place or not?
or do i always assume that when there are 2 elements in each reactant/ compound, that a reaction will always occur?

srry if this question is kinda confusing
it's just that i don't know the correct chemistry terms to use

and also I am in grade 11 chemistry so please easy with the chem terms
 
Chemistry news on Phys.org
There are two factors in whether a reaction will occur or not: Thermodynamics and Kinetics.

By thermodynamics I mean whether or not the products of the reaction have lower energy than the reactants. You can calculate that using heats of formation. For redox reactions you can use electrochemical potentials. (since the energy of the reaction is \Delta G = -nFE)

By kinetics I mean the reaction rate. If the products have lower energy, it's energetically beneficial to react, but it doesn't say anything about the rate at which that occurs. For instance, graphite has lower energy at room temperature/pressure than diamond does. But you don't see diamonds spontaneously turning into lumps of coal! Because it happens so very very slowly. The kinetics of a reaction you really have to measure experimentally.

Now if you look at Na2S, what can happen when you put it in water?
Well you could have the dissociation Na2S --> 2Na+ + S2-. From experience one can predict this - simply because few sodium salts are insoluble, and indeed, sodium sulfide is water soluble.

But the sulfide ion, S2-, is actually too basic to exist in water. (It has a pKa > 14) So in water, it will react to form a less basic pair of one hydrosulfide ion and one hydroxide ion:
S2- + H2O --> HS- + OH-

So your net reaction is:
Na2S + H2O--> 2Na+ + HS- + OH-

The electrochemical series doesn't come into this, because there's no redox reaction going on, just acid/base reactions.
So in this case, you reason from pKa values. (Or you could also use heats of formation to get the reaction energy. Again, this is equivalent, since pKa values and reaction energies are related)
 

Similar threads

  • · Replies 14 ·
Replies
14
Views
5K
  • · Replies 15 ·
Replies
15
Views
4K
Replies
5
Views
3K
  • · Replies 9 ·
Replies
9
Views
3K
Replies
1
Views
827
  • · Replies 4 ·
Replies
4
Views
4K
  • · Replies 9 ·
Replies
9
Views
6K
Replies
4
Views
2K
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
5K