How Does Adding Nitrogen Affect Pressure in a Sealed Vessel?

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Discussion Overview

The discussion revolves around the calculation of pressure changes in a sealed vessel when additional nitrogen gas is introduced. Participants explore the application of the ideal gas law and Dalton's law, considering assumptions about temperature and the method of calculation.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant presents a calculation using the ideal gas law, assuming constant temperature and arriving at a final pressure of 1.87 bar.
  • Another participant suggests that the lecturer may expect a calculation based on the initial and added moles of nitrogen rather than using partial pressures.
  • A different participant notes that the lecturer criticized the assumption of constant temperature in the initial solution.
  • Some participants argue that the method used by the original poster is valid and that differing methods do not necessarily indicate a mistake.

Areas of Agreement / Disagreement

There is no consensus on the correctness of the original solution method. Some participants support the original calculation, while others suggest that the lecturer's approach may be preferred.

Contextual Notes

Participants express uncertainty regarding the assumptions made about temperature and the method of calculation, highlighting that different approaches may yield valid results depending on interpretation.

frozen7
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A vessel of volume 0.2 m^3 contains nitrogen gas at 1.013 bar and 15 celsius. If 0.2 kg of nitrogen is now pumped into the vessel, calculate the new pressure when the vessel has returned to its initial temperature. The molecular weight of nitrogen is 28, and it may be assumed that the gas is a perfect gas. The universal gas constant is 8.314 kNm / kmoleK

I solve it in this way:

PV = nRT
P= nRT / V
= 200/28 x 8.314 x 288 x 1 / 0.2
= 85515 Pa
= 0.855bar

New pressure = 0.855bar + 1.013 bar
= 1.87 bar

The answer I get is same with the given correct answer. However, my lecturer told me that my solution is wrong even I got my final answer correctly. Can anyone explain to me what`s the reason?
Thanks in advance.
 
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I can't see anything wrong with your solution. You're simply using Dalton's law here, which should be ok. Did your lecturer comment on where your mistake exactly was?
 
Perhaps the instructor is expecting one to calculate the intial number of moles of N2 and then calculate the number of moles added, rather than using partial pressures.
 
He told me that because I assume the temperature is constant. The way he solves the problem is by finding the total mass of the nitrogen gas at the final moment and count the pressure by using ideal gas law.
 
Anyway, is my way to solve the problem correct?
 
Your way is correct. It's actually a bit more to the point. Your instructor did the long way around which is just a different way to do it.

Just because it is not the same method as your instructor's doesn't mean it isn't correct. You didn't get marked down, did you? That wouldn't be right unless it was specified how the problem should be approached.
 

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