How much will the atmospheric carbon dioxide change?

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SUMMARY

The discussion centers on calculating the percentage change in atmospheric carbon dioxide concentration after the release of 1014 kg of CO2. The initial atmospheric mass mixing ratio is given as 5.7 x 10-4 kg/kg, and the total mass of the atmosphere is approximated at 1018 kg. The percentage change is calculated to be 0.01%. Key contributors emphasize the importance of using the correct atmospheric pressure and density values, with a recommended scale height of approximately 7 km for accurate calculations.

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  • Knowledge of mass mixing ratios in atmospheric science
  • Basic principles of gas laws and their applications
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unscientific
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Homework Statement



Suppose ##10^{14} kg## of carbon dioxide was released into the atmosphere and absorbed completely, what is the percentage change of carbon dioxide concentration? Take initial atmospheric mass mixing ratio to be ## 5.7 \times 10^{-4} kg/kg##.

Homework Equations

The Attempt at a Solution



Using density of air as around ##29 g/mol##, the weight of the atmosphere is about ##10^{18} kg##. The percentage change is ##\frac{10^{14}}{10^{18}} \times 100 = 0.01%##? Where does the mixing ratio come in?
 
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Please show us how you calculated the mass of the atmosphere.

Chet
 
Chestermiller said:
Please show us how you calculated the mass of the atmosphere.

Chet

Taking pressure to be ##p_0 = 10^5 Pa##, I used ##\frac{4}{3}\pi R_E^3 p_0 \sim 10^{18} kg##. Sorry the ##29g/mol## bit was misleading.
 
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unscientific said:
Taking pressure to be ##p_0 = 10^5 Pa##, I used ##\frac{4}{3}\pi R_E^3 p_0 \sim 10^{18} kg##. Sorry the ##29g/mol## bit was misleading.
And (4/3) π RE3 represents what geometrically? Think about this carefully.
 
unscientific said:
Taking pressure to be ##p_0 = 10^5 Pa##, I used ##\frac{4}{3}\pi R_E^3 p_0 \sim 10^{18} kg##. Sorry the ##29g/mol## bit was misleading.
You can't just multiply the volume of the entire Earth by the air pressure at the surface of the Earth and think that you are getting the mass of the atmosphere. The units don't even match, and the Earth is not filled with air. What is the air density at the surface of the earth? Are you familiar with the barotropic equation?

Chet
 
Chestermiller said:
You can't just multiply the volume of the entire Earth by the air pressure at the surface of the Earth and think that you are getting the mass of the atmosphere. The units don't even match, and the Earth is not filled with air. What is the air density at the surface of the earth? Are you familiar with the barotropic equation?

Chet
Sorry I meant ##4\pi R_E^2 P_0##.
 
unscientific said:
Sorry I meant ##4\pi R_E^2 P_0##.
You forgot to divide by g.

Chet
 
The value ##29 (g/mol)## is equivalent to ## 1.29 (kg/m^3) ##. Taking the same density for about 3km and the Earth surface we have:
## \pi\times(6.4\times10^6)^2\times3000\times1.3 \approx 5\times10^{17} (kg) ##

For better answer we must use exponential law for pressure.
 
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theodoros.mihos said:
The value ##29 (g/mol)## is equivalent to ## 1.29 (kg/m^3) ##. Taking the same density for about 3km and the Earth surface we have:
## \pi\times(6.4\times10^6)^2\times3000\times1.3 \approx 5\times10^{17} (kg) ##

For better answer we must use exponential law for pressure.
The correct so-called scale height of the atmosphere is close to 7 km, rather than 3 km. But an easier way of doing this problem is to determine the weight of a column of air above each square meter. That would be 105 N. Assuming that the gravitational acceleration does not change much over the first few km, the mass of air over each square meter of surface would be 104 kg. Multiplying this by the area of the earth, one obtains 1.3 x 1018 kg. This compares with a value of 1.2 x 1018 obtained by taking your answer and multiplying it by 7/3.

Chet
 
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