How to Balance the Oxidation of H2S to Sulfate?

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SUMMARY

The oxidation of dissolved hydrogen sulfide (H2S) to sulfate (SO42-) by dissolved oxygen (O2) involves a two-step redox reaction. The balanced half-reactions are H2S + 1/2 O2 → S0 + H2O and S0 + 1 1/2 O2 + H2O → SO42- + 2H+. The redox couples identified are H2S/S0 and S0/SO42-, with oxygen being the oxidizing agent. The process requires balancing for charge and mass, specifically by adding electrons, water, and protons as necessary.

PREREQUISITES
  • Understanding of redox reactions and oxidation states
  • Familiarity with balancing chemical equations
  • Knowledge of half-reaction method for redox balancing
  • Basic chemistry concepts related to acids and bases
NEXT STEPS
  • Study the half-reaction method for balancing redox reactions
  • Learn about oxidation states and their significance in redox chemistry
  • Explore the role of oxygen as an oxidizing agent in chemical reactions
  • Investigate the environmental implications of H2S oxidation in natural waters
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Chemistry students, environmental scientists, and professionals involved in water treatment processes will benefit from this discussion on the oxidation of H2S to sulfate.

namata99
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Hello, I would need with this task:

Write a balanced equation for the oxidation of dissolved H2S to sulfate by dissolved oxygen. Indicate the oxidation states of the redox-sensitive elements involved.

- For each redox couple, write the oxidized and reduced species in an equation and balance the amount of element, except H and O.
- Balance electroneutrality by adding electrons.
- Balance the number of oxygen atoms by adding H2O.
- Balance the number of protons (H) by adding H+.
- Subtract the two half-reactions, canceling electrons to obtain the complete redox reaction.

Sulfide to Sulfate: H2S ->SO4 2-

Im not sure which are the redox couples and where to add electrons, but I've got this so far:

H2S + 1/2O2 -> S0 + H2O
S0 + 1 1/2O2 + H2O -> SO4 2- + 2H+

Can someone provide his advice or comment if this is correct and how to proceed further? Thanks!
 
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Why two steps oxidation and not a single step?

What is getting reduced?
 

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