Okay, I'll bite with a nearly wild guess. (It's been about a day with no guesses, so I'll give it a go.)
Even the dry atmosphere can refract light. And this is called
atmospheric lensing.
When looking at the sun at sunset or sunrise, you're not actually looking toward the true position of the sun at the time. The direction to the sun is actually lower than it looks. This is because the atmosphere bends the sunlight "down" (so to speak) making the direction to the sun appear farther up.
If you have a simple photovoltaic panel (PVP) and you want to get maximum efficiency, its best to make the PVP's surface normal to the direction of the sunlight. For most situations, this is easy enough by mounting the PVP on a equatorial mount, and have it track the Earth's rotation using a simple timer.
But such a setup would not be as efficient as it otherwise could be around sunrise or sunset due to the fact that the sunlight is not coming from the true direction of the sun, because of atmospheric lensing. That's not a big deal though. All that is lost is a little efficiency.
But wait, it gets weirder. Potentially a lot weirder.
Depending on the weather conditions anywhere between your location and down past the horizon, this effect can be less or more pronounced such as discussed in this link (The sun has already set, and yet then there's another sun! WTF?):
http://www.spaceweather.com/gallery/indiv_upload.php?upload_id=37810
It doesn't end there either. Many of you have probably seen a mirage at some time or another. A mirage can be considered another form of [atmospheric] lensing. When air is warmed by a hot surface, it can bend the light up making an additional image of the sun* (or sky or whatnot), seemingly coming from a pool of water (or mirror) on the ground (where no pool of water or mirror exists).
*(Edit: the actual scenario where an additional image is of the
sun itself is not likely to happen from a hot ground mirage, since the ground usually starts cooling off by sunset. But I'm just saying that the atmospheric lensing in the first link is not altogether different than a mirage.)
So how can this be problematic for a solar power enthusiast?** Well, there are more ways to harness solar power than a simple PVP.
One of them is concentrated photovoltaics
And there's also concentrated solar thermal.
Both of these methods require proper tracking of the sunlight.
Improper tracking of the sunlight, combined with concentrating that light, can cause bad things to happen. Very bad things: things such as awful fires, melting metal/concrete etc. There's going to be a focused beam of sunlight somewhere, so you'd better darn well make sure that it lands on something you want it to, and goodness sake not on something you don't want it to.
But what if (due to atmospheric lensing) there are suddenly two suns? Now that's a problem!
That's my guess anyway.
**(Edit: And even for a single non-concentrated PV system, such atmospheric lensing might throw off an automatic feedback sunlight tracking system, if the mount contains such a feedback tracking system. No actual danger in this situations, but I imagine it could completely throw off the mount's tracking abilities for awhile.)