How to calculate heat of reaction of a single replacement reaction?

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Discussion Overview

The discussion centers around calculating the heat of reaction for single replacement reactions in a laboratory setting. Participants explore the necessary measurements and calculations involved in determining the heat of reaction, specifically in the context of mixing copper(II) sulfate and iron in water.

Discussion Character

  • Experimental/applied
  • Technical explanation
  • Homework-related

Main Points Raised

  • One participant inquires about the appropriate measurements and calculations needed to determine the heat of reaction for single replacement reactions.
  • Another participant emphasizes the importance of providing details about the reaction, including the reagents, their phases, and any catalysts, to accurately determine ΔHrxn.
  • A participant mentions the use of calorimetry and the equation ΔE=mCΔT, expressing uncertainty about its application to a single replacement reaction in water.
  • Further clarification is sought regarding whether recording the temperature change and using ΔE=mCΔT would yield the correct heat of reaction, along with the need to adjust for the number of moles of reactants to find ΔH.
  • There is a suggestion that if the goal is to find the molar heat of the reaction, dividing by the number of moles of reactant would be necessary.

Areas of Agreement / Disagreement

Participants express varying levels of understanding regarding the calculations needed for determining the heat of reaction, with some uncertainty about the application of equations and the necessary adjustments for moles of reactants. The discussion does not reach a consensus on the best approach.

Contextual Notes

Participants highlight the need for specific details about the reaction setup and measurements, indicating that assumptions about the reaction conditions may affect the calculations. There is also mention of potential confusion regarding the relationship between ΔE and ΔH.

Who May Find This Useful

This discussion may be useful for students conducting experiments in chemistry, particularly those focusing on thermochemistry and calorimetry in single replacement reactions.

member 508213
In lab I am doing a series of single replacement reactions and I am curious how to calculate the heat of reaction for single replacement reactions and what measurements to take so I can calculate it?
 
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Since you're doing a lab I would assume that you were already taught the relevant equations and procedures...

Anyways, I think you should provide more details about the reaction.

What are the reagents? What are the phases of the reactants? Catalysts?

Details like these are important in order to determine the ΔHrxn.

As a refresher, the most common equations used to find the ΔHrxn are
  • ΔH°=∑ΔvpΔH°f(products)−∑ΔvrΔH°f(reactants)
  • ΔH=q=mcΔT
 
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I plan on mixing CuSO4 and Iron in water and I know that for calorimetry you use deltaE=mCdeltaT but I am unsure of how this would work with a single replacement reaction in water? What would be necessary to be able to obtain the overall heat of the reaction BY LAB not theoretical
 
To make more clear what I am trying to ask (sorry for not asking clearly) is:
Would it give me the correct heat of reaction if I put Iron and CuSO4 in water...recorded the change in temperature and used DE=mCDT?

But once I find DeltaE don't I have to do something else to find DeltaH like divide by the number of moles of reactant or something like that I forget? This is where my confusion is greatest..
 
Austin said:
But once I find DeltaE don't I have to do something else to find DeltaH like divide by the number of moles of reactant

Depends on what you aim at. If at the molar heat of the reaction (which is the most logical thing), then yes.
 

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