How to Calculate Mole Fractions and Molar Volume in a Thermodynamic System?

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SUMMARY

This discussion focuses on calculating mole fractions and molar volume in a thermodynamic system involving 0.1 kg of NaCl and 0.15 kg of sugar dissolved in 0.5 kg of water. The mole fraction of NaCl is determined to be 0.057, and the molar volume is calculated as 18 x 10-6 m3/mole. The calculations utilize the formula for relative mole fraction, Nk/ΣNj, and the definition of molar volume, V/ΣNk. The solution process emphasizes the importance of knowing molar masses for accurate conversions from mass to moles.

PREREQUISITES
  • Understanding of mole concept and conversions between mass and moles
  • Familiarity with molar mass calculations
  • Knowledge of thermodynamic principles
  • Basic proficiency in chemistry, particularly General Chemistry concepts
NEXT STEPS
  • Review the calculation of mole fractions using the formula Nk/ΣNj
  • Study the concept of molar volume and its calculation from total volume and moles
  • Explore the molar masses of common substances, including NaCl and sugar (C12H22O11)
  • Investigate the applications of mole fractions in thermodynamic systems
USEFUL FOR

Chemistry students, particularly those studying thermodynamics, as well as educators and professionals involved in chemical engineering and physical chemistry.

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Homework Statement


This question is problem 1.3.1 from Herbert Callen's textbook in Thermodynamics, second edition.

One tenth of a kilogram of NaCl and 0.15 kg of sugar ($C_{12} H_{22}O_{11}$ are dissolved in 0.5 Kg of pure water. The volume of the resultant thermodynamic system is $0.55\times 10^{-3}m^3$. What are the mole numbers of the three components of the system? What are the mole fractions? What is the molar volume of the system?
In the answers I have the following: Mole fraction of NaCl = 0.057, molar volume =$18\times 10^{-6} m^3/mole$.

How did they arrive at these answers? did they multiplied the ratios with Avogadro's number?

Homework Equations


Relative mole fraction is given by: N_k/\sum_{j=1}^r N_j if we have a mixture of $r$ substances, where this is defined as the molar fraction;
Molar volume is defined as V/\sum_{k=1}^r N_k.

The Attempt at a Solution


How do extract the moles of each substance here?

It's not written in the text.
 
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If you are attacking thermodynamics you should already know how to convert between masses and numbers of moles, this is GenChem101 which is prerequisite.

Do you know what the molar mass is?
 
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I have taken undergraduate thermal physics years ago, so I might have forgotten some stuff.

Anyhow, I solved it, thanks; I checked molar mass in wiki and it solved my problem.
 

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