How to calculate the solubility of AgCl in a solution containing NaCl?

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SUMMARY

The solubility of AgCl in a solution containing 0.0144 moles of NaCl was calculated using the solubility product constant (Ksp) of 1.7 x 10^-10. The common ion effect was applied, leading to the equilibrium expression Ksp = [Ag+][Cl-]. The calculation determined that the solubility of AgCl is 1.2 x 10^-8 mol/L, which converts to 1.8 x 10^-6 g/L. The molar mass of AgCl used in the calculations was confirmed to be 144 g/mol.

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brake4country
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Homework Statement


What mass of AgCl will dissolve in 1 L of water containing 0.0144 moles of NaCl. Ksp = 1.7 x 10^-10

Homework Equations


Ksp = [x][x] and ICE table

The Attempt at a Solution


So, the common ion effect is taking place here and the equilibrium taking place is:
AgCl(s) ↔ Ag+ + Cl-

Since excess Cl- will be present from the NaCl, the Na+ is just a spectator ion.

ICE table:
AgCl(s) ↔ Ag+ + Cl-
x 0 0.0144 M
-x x x
0 x 0.0144 + x

Ksp = [Ag+][Cl-] = 1.7 x 10^-10

(x)(0.0144 + x) = 1.7 x 10^-10

I assume that I can eliminate the x in the parentheses because it would be very small, thus:
0.0144x = 1.7 x 10^-10
x = 1.2 x 10^-8 mol/L
Converting to grams gives me 1.8 x 10^-6 g/L

I was wondering if someone wouldn't mind checking to see if my steps are accurate. Thanks in advance!
 
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What have you used for molar mass of AgCl? I got a slightly different result.
 
I used 144 g/mol. I will recheck my math.
 
Yes, x = 1.2x10^-8 mol/L
Thus, (1.2x10^-8 mol/L)(144 g/L) = 1.8x10^-6 g/L
 
brake4country said:
(1.2x10^-8 mol/L)(144 g/L) = 1.8x10^-6 g/L

No matter how many times you will write it, it won't get correct. Sorry.
 
Wait! The steps are more important! Can I get any advice on how I am approaching these problems?
 
Your approach is OK, the final result is not.
 
Borek is right, recheck your formula wt.
 

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