How can i calculate the solbilty of silver chloride?

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Discussion Overview

The discussion revolves around calculating the solubility of silver chloride (AgCl) in different solutions, specifically pure water and a 0.1M silver nitrate solution. It also explores the comparative solubility of silver chloride in aqueous ammonia versus water.

Discussion Character

  • Homework-related

Main Points Raised

  • One participant states the Ksp of silver chloride is 1.8x10-10 mol2dm-6 and attempts to calculate its solubility in pure water using the equation Ksp = [Ag+] x [Cl-].
  • Another participant asks for clarification on the units of solubility.
  • A different participant suggests converting moles of AgCl to grams and notes that a liter is equivalent to a cubic decimeter, implying a method for conversion to g dm-3.
  • There are questions raised about the solubility of silver chloride in a solution containing silver ions and the reasons for its increased solubility in aqueous ammonia compared to water.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the answers to parts b) and c), and the discussion remains unresolved regarding these aspects.

Contextual Notes

Participants have not fully addressed the assumptions or reactions involved in the solubility of silver chloride in ammonia, nor have they resolved the mathematical steps for converting solubility from moles to grams.

lioric
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Homework Statement



Ksp of silver chloride is 1.8x10-10 mol2dm-6 at RTP

a) calculate the solubility of silver chloride in gdm-3 in
i) pure water
ii) in 0.1M silver nitrate solution

b)Is silver chloride more soluble in water of in a solution containing silver ions. Why?
c) Why is silver chloride more soluble in aquouse ammonia than in water?


Homework Equations



AgCl = Ag+ x Cl-


The Attempt at a Solution



Ksp = [Ag+] x [Cl-]
1.8x10-10 = S x S

S= √1.8x10-10

Which i find the solubility. How do i convert it to g dm-3?

b)?
c)?
 
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What units will your solubility be in?

Before answering b try to solve a ii. c refers to additional reaction that takes place in the ammonia solution.
 
mol/dm3
 
Well, you know how many moles of AgCl dissolve in a liter of water. Just convert from moles of AgCl to grams of AgCl and realize that a liter is the same volume as a cubic decimeter.
 

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