How to Determine the Number of Pi Bonds in a Molecule Using the MO Model?

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To determine the number of pi bonds in a molecule using the MO model, it's essential to recognize that each double bond contributes one pi bond, while triple bonds contribute two. The calculation of pi bonds is influenced by the presence of unhybridized p-orbitals, which are necessary for pi bond formation. However, the number of unhybridized p-orbitals does not directly correlate with the total number of pi bonds. For practical purposes, counting the double and triple bonds in the molecular structure is the most straightforward method. Understanding these relationships clarifies the role of hybridization in bond formation.
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Homework Statement


HunOeH0.png

http://i.imgur.com/HunOeH0.png

Homework Equations


MO model

The Attempt at a Solution


as far as i know, number of pi bond is equal to 3 - the "power" of p (the hybridized bond formed)
the answer "4" is only calculated from the 4 elements' bond in part b, so why the central O and C atom is not considered with calculation of pi bond? Thanks!
 
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Each single bond consists of one sigma bond. Each double bond consists of one sigma bond and one pi bond.
 
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Does that means the number of pi bond is independent to degree of hybridization?
Thanks!
 
yecko said:
Does that means the number of pi bond is independent to degree of hybridization?
Thanks!
They are not independent as you generally need an unhybridized p-orbital to form a pi bond, but the number of unhybridized p-orbitals will not always be indicative of the number of pi bonds. It's much easier to simply count the number of double and triple bonds shown in the molecule.
 

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