How to express van der waals equation as virial expansion?

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SUMMARY

The van der Waals equation of state can be expressed as a virial expansion in powers of 1/Vm, leading to the derivation of the second and third virial coefficients, B and C. The equation is given by (p + a/V^2)(V - b) = RT. For argon at 273 K, the measured values are B = -21.7 cm³/mol and C = 1,200 cm⁶/mol². To find the parameters a and b in the van der Waals equation, one must manipulate the equation and apply the series expansion (1 - x)⁻¹ = 1 + x + x² + ... as indicated in Atkins' Appendix 2.

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  • Understanding of the van der Waals equation of state
  • Familiarity with virial expansions and coefficients
  • Basic knowledge of thermodynamics and gas laws
  • Ability to manipulate algebraic equations and series expansions
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  • Learn about the implications of the virial expansion in real gas behavior
  • Explore the use of the van der Waals equation in predicting gas properties
  • Review series expansions and their applications in thermodynamics
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Students in chemistry and physics, particularly those studying thermodynamics, gas laws, and the behavior of real gases, will benefit from this discussion.

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Homework Statement



Express the van der Waals equation of state as a virial expansion in powers of
1/Vm and obtain expressions for B and C in terms of the parameters a and b.
(Hint. The expansion you will need is (1–x) -1 = 1+x+x2+... . Series expansions
are discussed in Appendix 2 of Atkins.)
Measurements on argon gave B=-21.7 cm3.mol-1 and C=1,200 cm6.mol-2 for the
virial coefficients at 273 K. What are the values of a and b in the corresponding
van der Waals equation of state?



Homework Equations


Van der waals equation of state : ( p + a / V^2 ) ( V-b ) = RT


The Attempt at a Solution


Apparently this question is very common and found throughout the web. But I couldn't find any solution. I don't even know how to begin with expressing ;(
please help. thanks.
 
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Solve for P giving you a term containing

\frac{1}{V_m-b}

Factor out Vm then use the hint.
 

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