How to find the Density of Air with PV=nRT?

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SUMMARY

The discussion focuses on calculating the density of air using the Ideal Gas Law (PV=nRT) under standard conditions (1.00 atm and 273K). Participants emphasize the importance of air composition, specifically the weighted average molar mass of nitrogen and oxygen, which is approximately 28.913 g/mol. The formula d = PM/RT is confirmed as applicable for determining density at various temperatures and pressures, provided the ideal gas law is a valid approximation. The conversation highlights the necessity of understanding gas mixtures to accurately compute density.

PREREQUISITES
  • Understanding of the Ideal Gas Law (PV=nRT)
  • Knowledge of molar mass calculations for gas mixtures
  • Familiarity with standard temperature and pressure (STP) conditions
  • Basic concepts of gas composition and partial pressures
NEXT STEPS
  • Research the calculation of weighted average molar mass for gas mixtures
  • Learn about the application of the Ideal Gas Law in non-ideal conditions
  • Explore the concept of partial pressures in gas mixtures
  • Investigate the properties of gases at different temperatures and pressures
USEFUL FOR

Students in chemistry or physics, laboratory technicians conducting gas density experiments, and educators teaching the Ideal Gas Law and gas properties.

lc99
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Homework Statement


Let's say, P = 1.00 atm
and T =273K
and density of air at STP = 1.29 g/L

Homework Equations

The Attempt at a Solution


I'm not too sure...

PV = nRT
n = PV/RT
= P/RT = 1/(0.0821*273) *1.29 g/L ?
 
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PV=nRT alone is not enough, you need air composition as well.

For any gas: assume 1 m3 of gas, can you calculate number of moles? Mass? That will give you density instantly.

For air: air has no molar mass, as it is a mixture, but every mixture has its apparent molar mass (behaves as a gas of such), one that can be calculated as a weighted average of molar masses of the components.

Alternatively: assume 1 m3 of gas. Knowing the air composition, can you calculate volume occupied by the nitrogen? Or its partial pressure? Of other gases?
 
Borek said:
PV=nRT alone is not enough, you need air composition as well.

For any gas: assume 1 m3 of gas, can you calculate number of moles? Mass? That will give you density instantly.

For air: air has no molar mass, as it is a mixture, but every mixture has its apparent molar mass (behaves as a gas of such), one that can be calculated as a weighted average of molar masses of the components.

Alternatively: assume 1 m3 of gas. Knowing the air composition, can you calculate volume occupied by the nitrogen? Or its partial pressure? Of other gases?

im sort of confused because i was told to use the ideal gas law. the question is part of a lab I am doing and I am suppose to find the density of the air based on the lab's temperature and volume.
 
I gave you plenty of hints, have you tried to use them?
 
i
Borek said:
I gave you plenty of hints, have you tried to use them?
figured out how to get the moles of air.. so, the weighted avg of molar mass would be the a lot of gases wouldn't it?

i feel like I am missing some information. would finding the molar mass from the density of air at stp help to find molar mass of air?

so M = dRT/P at stp = 28.913 g/mol

so i can use the equation d = PM/RT for any temperature and pressure?
 
Last edited:
lc99 said:
i

figured out how to get the moles of air.. so, the weighted avg of molar mass would be the a lot of gases wouldn't it?

i feel like I am missing some information. would finding the molar mass from the density of air at stp help to find molar mass of air?

so M = dRT/P at stp = 28.913 g/mol

so i can use the equation d = PM/RT for any temperature and pressure?
You can use this equation at any temperature and pressure at which the ideal gas law is a good approximation for your particular gas.
 
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lc99 said:
the weighted avg of molar mass would be the a lot of gases wouldn't it?

Nope, enough to treat the air as a mixture of just nitrogen and oxygen, other ones are in minute quantities and can be safely ignored.
 
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Borek said:
Nope, enough to treat the air as a mixture of just nitrogen and oxygen, other ones are in minute quantities and can be safely ignored.

Thanks for the help!
 

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