How to measure an emission spectrum?

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SUMMARY

To measure an emission spectrum using a spectrophotometer with a grating monochromator, removing the exit slit is not necessary for all setups. For atomic emission spectra, a single-channel detector can effectively scan wavelengths without removing the exit slit. However, when utilizing a multichannel detector, such as a charge-coupled device (CCD), it is essential to open the exit slit to capture the full spectrum. This approach ensures optimal light collection and accurate measurements.

PREREQUISITES
  • Understanding of spectrophotometer components, specifically grating monochromators
  • Familiarity with emission spectroscopy techniques
  • Knowledge of detector types, including single-channel and multichannel detectors
  • Basic principles of atomic emission spectra
NEXT STEPS
  • Research the operation of grating monochromators in emission spectroscopy
  • Learn about the differences between single-channel and multichannel detectors
  • Explore the principles of atomic emission spectroscopy
  • Investigate the setup and calibration of spectrophotometers for emission measurements
USEFUL FOR

Researchers, laboratory technicians, and students in the fields of chemistry and physics who are involved in spectroscopy and emission analysis will benefit from this discussion.

gravenewworld
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Say I have a spectrophotometer that has a grating monochromator. If I want to measure emission instead of absorption from a lamp, could I just remove the exit slit? By removing the exit slit, doesn't all of the light just hit the sample?
 
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what kind of detector are you using? If you're using a lamp (continuum or for instance sodium lamp) and you're just measuring the atomic emission spectra than you could probably use a single channel detector to scan the wavelengths without removing the exit slit. If you're using a multichannel detector, for instance a charge couple detector, than you'll need to open up the exit slit.
 
Awesome, thanks!
 

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