How to Solve the Eigenfunctions of a Rigid Rotator in a Weak Electric Field?

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Homework Help Overview

The discussion revolves around the eigenfunctions of a rigid rotator in the presence of a weak electric field. The original poster presents a Hamiltonian for a rigid rotator and a perturbation due to an external electric field, seeking assistance in solving for the eigenfunctions under these conditions.

Discussion Character

  • Exploratory, Assumption checking, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the calculation of matrix elements of the perturbation and question the implications of the degeneracy of eigenfunctions. There are inquiries about the effects of the electric field on energy levels and the validity of the calculations presented.

Discussion Status

The conversation is ongoing, with participants providing insights into the calculations needed to evaluate the perturbation matrix. Some guidance has been offered regarding rewriting terms to facilitate integration, but there is no clear consensus on the implications of the results or the next steps.

Contextual Notes

Participants note that the original problem statement lacks a specific question, leading to some confusion about the focus of the discussion. There is also mention of the degeneracy of eigenfunctions and its relevance to the perturbation analysis.

hokhani
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Homework Statement



Consider the Hamiltonian for a rigid rotator, constrained to rotate in xy plane and with moment of inertia I and electric dipole moment\mu in the plane, as H_0=\frac{L_z^2}{2I}. Then suppose that a constant and weak external electric field,E, in the direction of x is applied so the perturbation is H'=-\mu E cos (\phi).

Homework Equations



The eigenfunctions of H_0 are double degenerate and the degeneracy is not removed even in high orders of perturbation. How should I solve it? could anyone please help me?

The Attempt at a Solution

 
Last edited:
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The problem statement doesn't include a question.

Have you calculated ##\langle m' | H' | m \rangle##? And found it to be always zero for ##m'\neq m##?
 
The degenerate eigenfunctions are |m\rangle=\frac{1}{\sqrt {2\pi}} e^(im\phi) and |-m\rangle=\frac{1}{\sqrt {2\pi}} e^(-im\phi) and \langle -m|cos(\phi)|m\rangle =0 (ms are integer). Hence all the elements of perturbation matrix between degenerate kets would be zero.
 
Last edited:
I made a quick calculation, and it seems indeed that the degeneracy is not lifted. How is that a problem? The field still shifts the levels.
 
Could you please give me your solution? Or at least, how much does the electric field move the levels?
 
You should calculate ##\langle m' | H' | m \rangle## yourself. Rewriting ##\cos \phi## in terms of exponentials helps in evaluating the integrals.
 
DrClaude said:
You should calculate ##\langle m' | H' | m \rangle## yourself. Rewriting ##\cos \phi## in terms of exponentials helps in evaluating the integrals.
Ok, it is very easy to calculate it:
\langle m' | H' | m \rangle=-\frac{\mu E}{2}(\delta(m',m+1)+\delta(m',m-1))
Making the H' matrix on the two degenerate kets, m and -m, we observe that all the four matrix elements are zero. Could you please tell me what is my mistake?
 
I'm sorry, but the I don't understand what question you are trying to answer.
 

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