How to understand the derivation for this process in QFT?

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SUMMARY

The discussion centers on the derivation presented in "Quantum Field Theory and the Standard Model" by Matthew Schwartz, specifically regarding the propagator and its relation to the S-matrix and the matrix element \(\mathcal{M}\). The author conducts the derivation without employing essential tools such as the LSZ formula, Wick's theorem, or Feynman diagrams, which leads to confusion among readers. Key points include the identification of the propagator as \(1/k^2\) and the relationship between initial and final states as two-particle states of definite momentum, with spin introduced as an additional degree of freedom. The conclusion is that the matrix element is determined entirely by spin, with the S-matrix spin part relating to projections onto the photon's spin states.

PREREQUISITES
  • Understanding of Quantum Field Theory (QFT) principles
  • Familiarity with the S-matrix formalism
  • Knowledge of propagators, specifically the Klein-Gordon propagator
  • Concepts of spin and tensor products in quantum mechanics
NEXT STEPS
  • Study the LSZ formula and its application in QFT
  • Learn about Wick's theorem and its role in perturbative calculations
  • Explore Feynman diagrams and their significance in particle interactions
  • Investigate the implications of spin in quantum states and scattering processes
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Physicists, graduate students in theoretical physics, and anyone studying Quantum Field Theory who seeks to deepen their understanding of derivations involving the S-matrix and propagators.

leo.
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I'm reading the book "Quantum Field Theory and the Standard Model" by Matthew Schwartz and I'm finding it quite hard to understand one derivation he does. It is actually short - two pages - so I find it instructive to post the pages here:
QIIom.png
The point is that the author is doing this derivation without any of the tools that would be needed. He doesn't use the LSZ formula, nor Wick's theorem, nor perturbation theory, nor Feynman Diagrams, absolutely nothing. Also, he doesn't use spinors, nor Dirac fields in order to deal with this.

Actually he discusses this prior to introducing all these things. Now, how he does this derivation is quite confusing for me.

I mean, he first talks about a propagator that would be 1/k^2. Now I know that the Fourier transform of the classical Klein Gordon propagator actually is 1/k^2, but I can't understand where this enters the discussion here, nor how this k he associates to a propagator is the total four-momentum.

I also don't understand this discussion that leads to the formula for \mathcal{M}. Up to this point the only thing the author has told about \mathcal{M} is that it is related to the S-matrix by \langle f | S- \mathbf{1}|i\rangle = i(2\pi)^4 \delta^4\left(\sum p_i^\mu - \sum p_f^\mu \right) \langle f | \mathcal{M} | i\rangle being |i\rangle, |f\rangle respectively the initial and final states.

Only in the next chapter he derives the LSZ formula that tells how to compute S and hence \mathcal{M} in terms of correlation functions, and only in the chapter after that he derives Wick's theorem to finaly compute this perturbatively.

So what is really going on here? How to understand this derivation the author presents? What is the point with this 1/k^2 propagator and why it relates to the center of mass energy? How this all leads to the formula for \mathcal{M}?
 
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Actually after thinking a little bit more about it, I believe I started to get the idea. The initial and final states are both two-particle states of definite momentum. My guess is that the author is saying that spin can be introduced here as another degree of freedom of these two particle states, included by a tensor product.

In other words, without spin we would have the initial state |p_1 p_2\rangle = |p_1\rangle \otimes_S |p_2\rangle being \otimes_S the symmetric tensor product. The author then considers that for each particle the one-particle state is actually |p_1; s_1\rangle = |p_1\rangle \otimes |s_1\rangle. In that setting we end up with the conclusion that

\langle f | S | i \rangle = \langle p_3 p_4 ; s_3 s_4 | S | p_1 p_2 ; s_1 s_2 \rangle

and considering that spin states and orbital states evolve independently, since S is just the time evolution operator acting between assymptotic states we have

\langle f | S | i \rangle = \langle p_3 p_4 | S_A | p_1 p_2 \rangle \langle s_3 s_4 | S_B | s_1 s_2 \rangle

now the one in the orbital states is related to the LSZ formula. There indeed all these cancelations involving the propagator occur and that would be just a dimensionless number as the author states. We are thus left with just the spin part. Finaly since the initial and final states are different, and since S = \mathbf{1}+iT, the identity part goes away, and we are left exactly with the conclusion that the matrix element is determined entirely by spin.

Is that the correct reasoning? The only last thing to understand is: why the S-matrix spin part is \langle s_3 s_4 | S_B | s_1 s_2 \rangle becomes a sum over projections onto the photon's spin states?
 

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