dlr said:
But what is actually happening, physically, at the molecular level?
Don't worry about it for now. Worrying about it at this point is hindering your understanding.
1) Specular Reflection When the photon "bounces off the surface" that means the photon was absorbed by an electron, and then emitted again, in some random direction, right? Same wavelength, so same energy, so how could any momentum (energy) have been imparted to the sail?
No! Specular reflection is "mirror-like". You are describe diffuse reflection.
Specular reflection:
Imagine you are the catcher in a baseball warmup. If the pitcher throws you a ball you throw it right back to the pitcher. If the first baseman throws you a ball you throw it to third. If the shortstop throws the ball you throw it back to the second baseman (who is between 1st and 2nd base). Wherever the ball comes from, you throw it at just that angle, but reversed. Just like a mirror.
The act of catching the ball imparts a certain amount of momentum to you. So does the act of throwing the ball. Regardless of where the ball came from, the net momentum imparted to you is always directly away from the pitcher.
Suppose that instead of balls coming from a random direction, the balls always come from third base. This is a solar sail: The vast, vast majority of the photons hitting the solar sail come from the Sun. An ideal solar sail is 100% specular. The net momentum transferred to the sail will be against the outward normal to the sail.
Diffuse reflection:
Again with the catcher analogy: Now when the third baseman throws the ball, you might throw the ball to first, or to third, or maybe even the manager who is lounging in the dugout. The direction is random,
but it is always somewhere in front of you. Catching the ball imparts a certain momentum to you, as does throwing it. Since your throw is in a random direction in front of you, over the long haul the momentum transfer from your throws will be aray from the pitcher. If the balls are coming from one particular direction (e.g., the Sun), you will also get a momentum transfer from the incoming balls. This is a non-ideal solar sail. Most of the incoming photons are reflected specularly, some are reflected diffusely, and some are absorbed.
2) Thermal What I don't see is how heating translates to linear motion at the molecular level, with individual electrons, protons and photons. The energetic photon comes in and it's electromagnetic field causes all of the electrons (and protons?) it passes to begin vibrating -- but back and forth, not in any continuous direction. The electrons are accelerating/decelerating as they bounce back and forth, so they are giving off photons. But how does that process of giving off photons cause the molecule move? And why consistently in one direction, instead of randomly? I mean, what is going on physically, at the level of the individual electron or molecule?
Suppose the object in question is a perfect absorber of photons. It is so very hungry for photons that it doesn't even emit any! That isn't possible of course; the intent here is to separate absorption and emission into two distinct processes. This perfect absorber will feel a thrust directly against the Sun because these gobbled-up photons transfer momentum to the object.
Now let's look at emission only. Suppose the object is in deep space, far from any star, and has some heat source inside it so it doesn't cool off as it is emitting photons. Each emitted photon will impart a thrust on the object. If the object has a uniform temperature, this imparted thrust will average out to nothing because it is radiating uniformly. That is no longer true if the heat source is very close to one surface. Now one side will be much hotter than the opposite side. The radiation will no longer be uniform. The object will experience a thrust directed away the hot side of the object.
Now let's put absorption and emission together. Suppose the object is keeping one side always facing the Sun. This sunlit side will be warmer than the perpetually shaded side, the there will be thrust away from the Sun due to this non-uniform temperature. The object is absorbing photons, so this also generates a thrust away from the Sun.