Impact of Temperature on Fuel Cell Work Output

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As temperature increases, the maximum work output from the fuel cell reaction decreases. This is derived from the relationship between Gibbs free energy (G), enthalpy (H), and entropy (S), where both dH and dS are negative for the reaction. The equation w_max = -RT ln(K) indicates that as temperature (T) rises, the value of w_max becomes more negative due to the positive nature of ln(K). Therefore, the conclusion is that increased temperature leads to decreased work output from the fuel cell. This understanding is crucial for optimizing fuel cell performance.
eraemia
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Homework Statement



2 H2(g) + O2(g) 2 H2O(l) K = 1.28e83

As temperature increases, does the maximum amount of work obtained from the fuel cell reaction increase, decrease, or remain the same?

Homework Equations



1. G = -RTln(K)
2. dG = dH - tdS
3. w_max = dG

The Attempt at a Solution



Okay, using formation values, I calculated that for this reaction, both dH and dS are < 0.

If dG = w_max (eq. 3), then w_max = -RT ln K (1 and 3)
Since ln(K) is positive, the larger the T, the more negative w_max.
Thus, as T increases, w_work decreases?

Is that right? Thanks.
 
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eraemia said:
Thus, as T increases, w_work decreases?

Is that right? Thanks.
Sounds good.
 

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