Internal combustion engine problem.

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SUMMARY

The discussion centers on calculating the work done by an internal combustion engine operating on octane, with specific parameters including an enthalpy of combustion of -5512 kJ/mol, a mass of 3 kg for 1 gallon of fuel, and temperatures of 2000 degrees C and 800 degrees C. The total enthalpy calculated is -145053 kJ, with a total of 26.3 moles of octane involved. Key ambiguities in the problem include the actual amount of octane being used and the starting conditions of temperature and pressure, which are critical for accurate calculations.

PREREQUISITES
  • Understanding of thermodynamics, specifically enthalpy and combustion processes.
  • Familiarity with the properties of octane, including its molar mass of 0.1142 kg/mol.
  • Knowledge of internal combustion engine operation and thermodynamic cycles.
  • Basic skills in stoichiometry and mole calculations.
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  • Research the ideal gas law and its application in combustion engines.
  • Learn about the thermodynamic cycles relevant to internal combustion engines, such as the Otto cycle.
  • Study the effects of temperature and pressure on combustion efficiency.
  • Explore methods for calculating work done in thermodynamic systems, including the first law of thermodynamics.
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fraggedmemory
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An internal combustion engine runs on octane, the enthalpy of combustion is -5512 kJ/mol. The mass of 1 gallon of fuel is 3 kg.
The engine temperature is 2000 degrees C and the exit temperature is 800 degrees C. What is the work done?

The total enthalpy is -145053 kJ. The total number of moles of octane is 26.3. The molar mass of octane is .1142 kg/mol

I spent a good deal of time on this, and I am not sure how to conceptualize this problem.

*I edited the problem so you don't have to read the poorly written original problem. *
 
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fraggedmemory said:
An internal combustion engine runs on octane, the enthalpy of combustion is -5512 kJ/mol. The mass of 1 gallon of fuel is 3 kg.
The engine temperature is 2000 degrees C and the exit temperature is 800 degrees C. What is the work done?

The total enthalpy is -145053 kJ. The total number of moles of octane is 26.3. The molar mass of octane is .1142 kg/mol

I spent a good deal of time on this, and I am not sure how to conceptualize this problem.

*I edited the problem so you don't have to read the poorly written original problem. *
You've mentioned you've spent a good deal of time on this, so show us what you've come up with so far! We can't help you unless you show us your work.

That said, I think I'd like to see original problem anyway. The way it's written above contains multiple ambiguities. For example, are we dealing with 1 gallon of octane, 3 kg of octane, or some other amount of octane? It can't be both 1 gallon and 3 kg of pure octane, since the density of octane is 0.703 \ \mathrm{gm/cm^3} = 2.661 \ \mathrm{kg/gal}. So the first question is, how much actual ocatane are we dealing with here?

The problem states the "ending" temperature is 800 deg C, but what about the "starting" temperature? Is that the same as the engine temperature? What about pressure? Is the starting pressure the same as the ending pressure?

I think we can assume that the reaction involves oxygen and the byproducts are water and carbon dioxide, but what are the starting temperature and pressure of intake gas?

My point of all this is there seems to be some information left out here and there.
 

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