Is Neutralization Reaction Always Equivalent to Titration?

  • Thread starter Thread starter SciencePF
  • Start date Start date
  • Tags Tags
    Reaction
Join the discussion
Ask a follow-up here, or get your own question answered by working scientists, mathematicians and engineers — people, not an autocomplete.
Real named experts · corrections over time · the nuance an AI answer skips
3 replies · 3K views
SciencePF
Messages
55
Reaction score
0
Is it correct to talk about a "Neutralization Reaction" when we make a titration of a weak acid with a strong base, or it is only correct if we titrate a strong acid with a strong base or a strong base with a strong acid? Thanks.:smile:
 
Chemistry news on Phys.org
neutralisation involves rxn between H+ and OH-
whenever there is a rxn between an acid and a base, it is always a neutralisation one!

moreover, a weak acid will ionise completely during neutralisation.

as the OH- reacts with the H+ from the weak acid, the latter H+ decreases in concentration. According to Le Chatelier's principle, the weak acid will dissociate to produce even more H+! eventually, the weak acid will end up dissociating completely!
 
But final solution, at 25 ºC, has not pH=7! i.e. is not a neutral solution!
 
Technically, a neutralization reaction produces a pH 7 solution of salt. This may require more titrant than an equinormal amount if weak acids -strong bases or strong acid - weak bases are used. So, in the broadest sense, a neutralization reaction is not always a titration unless strong acids and strong bases are being used.