Is the Energy Expectation Value Always Real and Above a Minimum Potential?

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Discussion Overview

The discussion revolves around the theorem stating that if the potential V(x, t) is greater than or equal to a constant V0, then the energy expectation value is real and at least V0 for any normalizable quantum state. Participants are exploring the proof of this theorem, particularly focusing on the inequality involving the energy expectation value and its components.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • Some participants question the validity of the inequality = (ħ²/2m)∫∇ψ*∇ψ d³x + ∫ Vψ*ψ d³x ≥ ∫ V0ψ*ψ, seeking clarification on why it holds true.
  • Others suggest that the first integral is non-negative due to the modulus squared of ∇ψ, while the second integral's relationship to V0 is debated, especially considering V0 could potentially be negative.
  • One participant proposes that the reasoning for the inequality could be that ∫ (V - V0)(ψ*ψ) d³x is non-negative since both terms are non-negative, leading to a conclusion about the integral's positivity.
  • Another participant refers to a theorem from calculus regarding integrals and inequalities, suggesting that if one function is greater than another over an interval, the integral of the first function will also be greater than the integral of the second.
  • There is a discussion about the conditions under which the inequality holds, with some participants emphasizing the need for clarity on the assumptions involved.

Areas of Agreement / Disagreement

Participants express varying levels of understanding regarding the inequality, with some agreeing on the positivity of certain integrals while others remain uncertain about the implications of V0 being negative. The discussion does not reach a consensus on the reasoning behind the inequality.

Contextual Notes

There are unresolved questions about the assumptions underlying the theorem and the specific conditions that must be met for the inequalities to hold. The discussion also highlights the potential for confusion regarding the definitions and properties of the involved mathematical terms.

dyn
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Hi
A theorem states that if V(x , t) ≥ V0 then <E> is real and <E> ≥V0 for any normalizable state. The proof contains the following line

<E> = (ħ2/2m)∫∇ψ*∇ψ d3x + ∫ Vψ*ψ d3x ≥ ∫ V0ψ*ψ

Can anybody explain why that inequality is true ?
Thanks
 
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dyn said:
Hi
A theorem states that if V(x , t) ≥ V0 then <E> is real and <E> ≥V0 for any normalizable state. The proof contains the following line

<E> = (ħ2/2m)∫∇ψ*∇ψ d3x + ∫ Vψ*ψ d3x ≥ ∫ V0ψ*ψ

Can anybody explain why that inequality is true ?
Thanks
Why do you think?

Hint: when do we have ##A= B + C \ge C##?
 
That would be if B ≥ 0 ; but why is the 1st integral ≥ 0 and why does the 2nd integral change from V to V0 ?
 
dyn said:
That would be if B ≥ 0 ; but why is the 1st integral ≥ 0 and why does the 2nd integral change from V to V0 ?
What do you think? Show some effort!
 
PeroK said:
when do we have ##A= B + C \ge C##?
The two ##V## integrals are not the same, so the form of the equation is not exactly ##B + C \ge C##. It's more like ##B + C \ge D##, where we are given that ##C \ge D##.
 
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dyn said:
Can anybody explain why that inequality is true ?
Have you tried to evaluate the signs of each term? If each term is positive, and you are already given that ##V \ge V_0## for all ##V##, what can you conclude?
 
PeterDonis said:
The two ##V## integrals are not the same, so the form of the equation is not exactly ##B + C \ge C##. It's more like ##B + C \ge D##, where we are given that ##C \ge D##.
Or ##B + C \ge C \ge C_0##
 
dyn said:
That would be if B ≥ 0
Can you show that this is the case for what you gave in the OP?
 
dyn said:
Hi
A theorem states that if V(x , t) ≥ V0 then <E> is real and <E> ≥V0 for any normalizable state. The proof contains the following line

<E> = (ħ2/2m)∫∇ψ*∇ψ d3x + ∫ Vψ*ψ d3x ≥ ∫ V0ψ*ψ

Can anybody explain why that inequality is true ?
Thanks
The 1st integral is the integral of the modulus squared of ∇ψ which is always a positive quantity so that intgral will always be ≥ 0. It seems obvious that ∫Vψ*ψ d3x ≥ ∫ V0ψ*ψ d3x but what is the actual reason , after all V0 could be negative ?
 
  • #10
dyn said:
after all V0 could be negative ?
Does that matter?
 
  • #11
dyn said:
It seems obvious that ∫Vψ*ψ d3x ≥ ∫ V0ψ*ψ d3x but what is the actual reason , after all V0 could be negative ?
Yes that is very obvious indeed for someone that has study integrals and inequalities and the reason is contained in any decent calculus textbook, but it might not be obvious to you. (don't get me wrong I know you probably have studied calculus but you missed that chapter on integrals and inequalities, these days the basics are not being taught well enough)

I ll give you a mini theorem (lemma) that is contained in any decent calculus textbook as I said and I think you should be able to infer the rest.
Theorem (on integrals and inequalities)
""If ##f,g## are two integratable functions in ##[a,b] ##and ##f(x)\geq g(x)## for all ##x\in[a,b]## then the following inequality holds $$\int_a^b f(x)dx\geq\int_a^b g(x) dx$$.""
 
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  • #12
dyn said:
The 1st integral is the integral of the modulus squared of ∇ψ which is always a positive quantity so that intgral will always be ≥ 0. It seems obvious that ∫Vψ*ψ d3x ≥ ∫ V0ψ*ψ d3x but what is the actual reason , after all V0 could be negative ?
Is the argument for the inequality as follows ?
∫ (V - V0) (ψ*ψ) d3x ≥ 0 because both brackets are always ≥ 0 so it is an everywhere positive integral then i just turn the integral into 2 terms and take the V0 term over to the other side. Is that the correct reasoning ?
 
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  • #13
Does the my reasoning in #12 explain in simple terms the inequality lemma in #11 ?
 
  • #14
dyn said:
Does the my reasoning in #12 explain in simple terms the inequality lemma in #11 ?
Yes it does, that's the way the lemma in 11 is proved, that the function u=f-g is always positive, and the integral of a positive function is a positive number e.t.c.
 
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  • #15
Thank you everyone
 
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