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Why does nitrate (NO3-) have an oxidation state of +5? Doesn't it have 4 bonds to oxygen? Shouldn't that give it an oxidation state of +4?
The oxidation state of nitrate (NO3-) is definitively +5, despite having four bonds to oxygen. This is because oxidation numbers are determined by the overall charge and electron distribution rather than merely the number of bonds. In the nitrate ion, the nitrogen atom forms one double bond, one dative bond, and one single bond with oxygen, resulting in a total of five effective bonds. This configuration leads to the nitrogen's oxidation state being +5, as confirmed by sources such as Chembuddy.
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