Any identity ##e## would have to satisfy ##f = e*f##, for all ##f## in the domain, which forces
$$F(s) = \mathcal{L}[f(t)] = \mathcal{L}[e*f(t)] = E(s)F(s)$$
So for any given ##s##, if there is some ##f## in the domain for which ##F(s) \neq 0##, then we can divide by ##F(s)## to force ##E(s) = 1##. Moreover, for the special case ##f = e##, we have ##E(s) = E(s)E(s)##, which means that ##E(s)## must be either 0 or 1 for every ##s##. I believe that if ##E## is the Laplace transform of an integrable function ##e##, then ##E## must be continuous (I know this is true for the Fourier transform), in which case this forces ##E(s) = 1## for all ##s##.
Thus there is only one identity candidate, and that is a "function" ##e## satisfying ##\mathcal{L}[e(t)] = 1##. Indeed there is no such function, so we would have to enlarge the domain to include the Dirac delta distribution ##\delta##.
But the domain also needs to include inverses, i.e. for every ##f## there must be some ##g## such that ##f*g = \delta##. This will not be possible in general. (Consider ##f = 0## for one extreme case.)