Strictly speaking, ##\mathbb{R}^n## is just the set of n-tuples {(x1,..,xn)}. To make it a vector space you have to specify two sets, the set of vectors and the field of scalars, then define how the vector elements add and what the product of a scalar and a vector is.
That we commonly think of ##\mathbb{R}^n## as the natural vector space ##\{\mathbb{R}^n, \mathbb{R}\}## is just a convenient shorthand.
Is there only one way to do that with ##\mathbb{R}^n## as a set of vectors over the field ##\mathbb{R}##?
What if I take the n-tuples ##\mathbb{C}^n## over the field ##\mathbb{R}##? Doesn't that make a vector space in the obvious way?