No worries, jaysun. But since you are self-learning the material, let's keep it in the Homework Help forums.
On your question, are you familiar with graphs? That might help to give you some intuition as to how to solve this. I'd start by drawing an distance versus time plot (time t on the horizontal axis, and distance d on the vertical). At time t=0 (the whole d axis) put the head of the train on d=92m, and the tail at d=0. Put the car also at d=0 at time t=0 (the place where the two axes cross).
Now, the car is moving with some constant velocity, so draw a straight line up and to the right from the origin. The slope of this line (actually the rise divided by the run) is delta_d/delta_t, or the change in position with respect to time, which is the velocity, right? Since the velocity is constant, this line is straight. Don't worry that you don't know the actual velocity number yet -- we're just making a plot to help figure out the problem.
Now, the train moves differently. Since the head and tail are connected rigidly, we can just make parallel plot lines for each. They will stay the same delta_d distance apart (92m) the whole time. So plot two parallel parabolas, the tail position parabola starts at the origin, and goes up and to the right with a shape of d=Ct^2, where C is some coefficient. Draw a similar parabola up an to the right from the head of the train, starting at t=0 and d=92m.
Now, do you see how the car is even with the tail of the train at first, then at some time (we are told 14s), it is even with the head (and maybe passes it for a bit? I don't know), but the train keeps accelerating to higher speeds than the car, and the straight car line gets crossed one last time by the parabola line for the tail of the train?
Okay, now that you have the graph, does that help you to see how to set up the equations? The 4th equation that you list above is the right one to start with, but what is Vo for the train if it starts at rest?
I think you'll end up with a couple simultaneous equations, and solving those should get you the answers. I'll check back in a bit to see how you're doing.