Justifying Log Approximation for Low \tau and High E_o

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Homework Help Overview

The discussion revolves around the justification for a logarithmic approximation in the context of calculating the partition function for rotational degrees of freedom of a single molecule, specifically under the condition where \(\tau\) is much smaller than \(E_o\).

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore the validity of the approximation \(\log(1 + 3e^{-2\frac{E_o}{\tau}}) \approx \log(3e^{-2\frac{E_o}{\tau}})\) and question the conditions under which it holds, particularly whether the argument of the logarithm is sufficiently large.

Discussion Status

The discussion is ongoing, with participants questioning the assumptions behind the approximation and the context in which it is applied. Some have suggested seeking clarification from the teacher regarding the conditions for the approximation's validity.

Contextual Notes

There is a mention of the assumption that \(\tau\) is much less than \(E_o\) and the nature of the logarithmic function being used (natural logs). Additionally, there is uncertainty about the size of the argument to the logarithm and its implications for the approximation.

eep
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Hi,
In his notes, our teacher makes this approximation:

[tex] \log(1 + 3e^{-2\frac{E_o}{\tau}}) \approx \log(3e^{-2\frac{E_o}{\tau}})[/tex]

For [itex]\tau << E_o[/itex]

Also, and I don't think this matters, the logs are assumed to be natural logs.

I was wondering what the justification for this was...
 
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For many purposes, [itex]x \approx x+1[/itex] when x is large.
 
But x isn't large in this case?
 
There doesn't appear to be much. What's the context? Is [tex]3e^{-2\frac{E_o}{\tau}}[/tex] very large?

EDIT: In that case, ask your teacher
 
I thought maybe you had forgotten [itex]\tau < 0[/itex]. If the argument to log isn't large, then that's not a good approximation.
 
Sorry I hadn't quite finished editing my post when people started replying. We're trying to calculate the partition function for rotational degrees of freedom for a single molecule. So we have an infinite sum which we keep only the first two terms in the [itex]\tau << E_o[/itex] limit (the terms in the log). We then want to calculate the average energy which is where the log comes from, and he then makes that approximation. I guess I'll just have to ask him.
 
Are you sure there's a log around that second expression? Because [itex]log(1+x)\approx x[/itex] for x very small.
 
Ah, yes. I just misread the notes! Thanks anyways!
 

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