How Does Electron Uncertainty Compare to Helium Atom Size?

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SUMMARY

The average kinetic energy of an electron in a ground-state helium atom is calculated to be 2.4x10^3 kJ/mol, leading to an electron velocity of 3.0x10^6 m/s. With a 10% uncertainty in this velocity, the minimum uncertainty in the electron's position is determined to be Δx=2.0e-10 m. This uncertainty is compared to the effective radius of a helium atom, which is 130 pm (1.30e-10 m), indicating that the calculated uncertainty is a significant fraction of the atom's radius.

PREREQUISITES
  • Understanding of kinetic energy calculations in quantum mechanics
  • Familiarity with the Heisenberg uncertainty principle
  • Basic knowledge of atomic structure and effective radius
  • Proficiency in unit conversions, particularly between kJ/mol and m/s
NEXT STEPS
  • Study the Heisenberg uncertainty principle in detail
  • Learn about quantum mechanics and atomic models
  • Explore the implications of electron velocity and position uncertainty
  • Investigate the properties of helium and other noble gases
USEFUL FOR

Students in physics, particularly those studying quantum mechanics, as well as educators and researchers interested in atomic structure and electron behavior.

littlebearrrr
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Homework Statement



(NOTE: I solved the first two parts of this problem, but I included it anyway so you have background knowledge for the third question)

The average kinetic energy of an electron in a ground-state helium atom is 2.4x10^3 kJ/mol.

A. What is the corresponding electron velocity?

B. An experiment measures this velocity with an uncertainty of 10%. Calculate the minimum uncertainty in the position of the electron for this experiment.

C. The effective radius of a helium atom is 130 pm. Is the uncertainty in the position you calculated in B a significant fraction of this radius?

Homework Equations



A. KE=(1/2)mv^2

B. Δx*Δv≥ h/(4pi)m

C. N/A


The Attempt at a Solution



A. Just multiplied 2.4e3 kJ/mol by (1 mole/6.022e23 electrons) and used the above equation to solve for v. Got 3.0e6 m/s.

B. Took 10% of my velocity, plugged that into the above inequality. Obtained Δx=2.0e-10 m (can someone check if this is right?)

C. If the above answer in B is right, do I just take that answer and divide it by 1.30e-10 m to get my answer for C?
 
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littlebearrrr said:
B. Took 10% of my velocity, plugged that into the above inequality. Obtained Δx=2.0e-10 m (can someone check if this is right?)
That looks correct.

littlebearrrr said:
C. If the above answer in B is right, do I just take that answer and divide it by 1.30e-10 m to get my answer for C?
I don't think that C calls for a numerical result, rather an appreciation of the result of B compared to the effective radius.
 
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Hey DrClaude, thanks for your help/checking my answers again :)
 

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