Kinetic Theory - Mass on a piston

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Homework Help Overview

The discussion revolves around a cylinder containing an ideal gas with a movable piston. The problem explores the effects of temperature changes on pressure and volume, particularly focusing on the relationship between the gas pressure, the weight of the piston, and the behavior of gas molecules as temperature increases.

Discussion Character

  • Conceptual clarification, Assumption checking, Exploratory

Approaches and Questions Raised

  • Participants discuss the implications of temperature increases on gas pressure and volume, with some suggesting that pressure must change while others argue it remains constant due to the weight of the piston. Questions arise regarding the balance of forces on the piston and the nature of pressure exerted by the gas.

Discussion Status

There is an ongoing exploration of the relationship between gas pressure and the weight of the piston. Some participants express confusion about why the pressure is considered constant despite the increase in gas temperature, while others clarify the conditions under which pressure remains constant. The discussion reflects a mix of interpretations and attempts to reconcile different viewpoints.

Contextual Notes

Participants are navigating assumptions about the system, including the mass of the piston and the nature of the gas expansion. The discussion also touches on the concept of reversible versus irreversible expansion, highlighting the complexities involved in applying the ideal gas law under different conditions.

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Homework Statement


A cylinder containing an ideal gas is in vertical position and has a piston of mass ##M## that is able to move up or down without friction (Fig. 13.2). If the temperature is increases,
IMG_20170304_170404875.jpg
...Fig (13.2)
(a) both ##p## and ##V## of the gas will change.
(b) only ##p## will increase according to Charles' Law.
(c) ##V## will change but not ##p##.
(d) ##p## will change but not ##V##.

Homework Equations



##pV=nRT##
##ΔU=q+w##[/B]

The Attempt at a Solution


The answer that is given is (c) and the reasoning is that the pressure (=Mg/A) is constant. But I don't get it. I think that the pressure of the gas will increase because as the temperature increases, the molecules will start hitting the walls of the container with greater speed causing an increase in pressure. Also as the temperature increases, the internal energy will increase and work will be done by the system on the piston thus lifting it up. This will cause an increase in volume. So, as the pressure and the volume are changing the correct answer would be (a).
Could someone please explain to me why I'm wrong?
 
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danielbaker453 said:
The answer that is given is (c) and the reasoning is that the pressure (=Mg/A) is constant. But I don't get it. I think that the pressure of the gas will increase because as the temperature increases, the molecules will start hitting the walls of the container with greater speed causing an increase in pressure.

That's correct but what happens next is incorrect. I mean what happens if the pressure inside is greater than Mg/A?
 
As the volume increases, the molecules get further apart, so the frequency of collisions with the piston decreases.
 
CWatters said:
That's correct but what happens next is incorrect. I mean what happens if the pressure inside is greater than Mg/A?
If the pressure inside is greater, the piston will be pushed up. This means that the pressure is changing and so is the volume(due to expansion). Am I right?
 
danielbaker453 said:
If the pressure inside is greater, the piston will be pushed up. This means that the pressure is changing and so is the volume(due to expansion). Am I right?
No. The pressure will stay constant.
 
Chestermiller said:
No. The pressure will stay constant.
But the pressure exerted by the gas has increased. I do understand that the pressure on the gas due to the mass 'M' is constant (=Mg/A) but isn't 'p' the pressure exerted by the gas?
 
danielbaker453 said:
But the pressure exerted by the gas has increased. I do understand that the pressure on the gas due to the mass 'M' is constant (=Mg/A) but isn't 'p' the pressure exerted by the gas?
If the piston is massless and frictionless, what does the force balance on the piston tell you?
 
Chestermiller said:
If the piston is massless and frictionless, what does the force balance on the piston tell you?
In that case, the only force on the piston is that exerted by the gas molecules.
 
danielbaker453 said:
In that case, the only force on the piston is that exerted by the gas molecules.
Sorry. I forgot that the piston is supposed to have mass. So, let me rephrase my question: If the piston is frictionless, what does the force balance on the piston tell you?
 
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  • #10
Chestermiller said:
Sorry. I forgot that the piston is supposed to have mass. So, let me rephrase my question: If the piston is frictionless, what does the force balance on the piston tell you?
Got it!
Now, the force exerted by the gas equals the weight of the mass 'M'.
Fgas=Mg
If we divide both sides by the area 'A'
Pgas=Mg/A
The pressure will be constant.
Thank you very much for your help!
P.S. since here Pexternal=Pinternal, is this a case of reversible expansion?
 
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  • #11
danielbaker453 said:
Got it!
Now, the force exerted by the gas equals the weight of the mass 'M'.
Fgas=Mg
If we divide both sides by the area 'A'
Pgas=Mg/A
The pressure will be constant.
Thank you very much for your help!
P.S. since here Pexternal=Pinternal, is this a case of reversible expansion?
The gas force per unit area on the inside face of the piston always matches the ##P_{ext}## (by Newton's 3rd law), irrespective of whether the expansion is reversible. But, in an irreversible expansion, the gas pressure in the cylinder varies with spatial position and the force per unit area at the piston face includes viscous stresses. So, in an irreversible expansion, the ideal gas law (or other equation of state) cannot be applied globally to the gas.
 
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  • #12
+1

At some point the piston will stop accelerating. If it's not accelerating the net force on it is zero so the force due to the pressure of the gas must equal the force due to gravity.
 
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