Lennard-Jones-Potential: Equation of motion

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SUMMARY

The discussion centers on deriving the equation of motion from the Lennard-Jones potential, specifically the equation U_{LJ}(\vec{r}) = D \Big[ \big( \frac{R}{r}\big)^{12} - 2* \big(\frac{R}{r} \big)^{6} \Big]. The user successfully computes the force as \vec{F} = 12 * D * \Big[ \big(\frac{R^6}{x^7}\big) - \big(\frac{R^{12}}{x^{13}}\big) \Big] using the relation \vec{F} = -\nabla U_{LJ}(\vec{r}). However, there is confusion regarding whether the final output should explicitly include time dependence, as the task requested an equation of motion.

PREREQUISITES
  • Understanding of the Lennard-Jones potential and its mathematical formulation.
  • Familiarity with Newton's second law of motion and its application in deriving equations of motion.
  • Knowledge of vector calculus, specifically the gradient operator.
  • Basic proficiency in manipulating derivatives and algebraic expressions in physics.
NEXT STEPS
  • Research the derivation of equations of motion from different potential energy functions.
  • Study the application of the gradient operator in physics, particularly in force calculations.
  • Explore time-dependent motion equations in classical mechanics.
  • Learn about the implications of conservative forces in the context of potential energy.
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This discussion is beneficial for physics students, particularly those studying classical mechanics and potential energy, as well as educators looking for examples of force derivation from potential functions.

TanGeriN
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Homework Statement



Hello everybody,

i have got the following task to solve.

Given the following potential: U_{LJ}(\vec{r}) = D \Big[ \big( \frac{R}{r}\big)^{12} - 2* \big(\frac{R}{r} \big)^{6} \Big]
where r means the length of \vec{r}

Give an equation of motion explicitly of the form m * \frac{\partial^{2} \vec{x}}{\partial t^{2}} = -\nabla U_{LJ}(\vec{r})

Homework Equations



I normally have no problem to find the conservative force for a given potential. I would simply use this equation: \vec{F}(\vec{r}) = -\nabla U(\vec{r})

The Attempt at a Solution



I finally got this equation of motion with respect to x:

\vec{F} = - \frac{\partial}{\partial x} U_{LJ}(\vec{r})\\<br /> \\<br /> \vec{F} = - \Bigg[ \frac{\partial}{\partial x}D \Big[ \big(\frac{R}{x}\big)^{12} - 2* \big(\frac{R}{x}\big)^{6} \Big] \Bigg] \\<br /> \\<br /> \vec{F} = - \Bigg[ D * \Big[ 12 * \big(\frac{R}{x}\big)^{11} * \big(-\frac{R}{x^2}\big) - 12* \big(\frac{R}{x}\big)^{5} * \big(-\frac{R}{x^2}\big) \Big] \Bigg] \\<br /> \\<br /> \vec{F} = 12 * D * \Big[ \big(\frac{R^6}{x^7}\big) - \big(\frac{R^{12}}{x^{13}}\big) \Big] \\

I am not sure if this is really the solution to the task above, because it was explicitly asked for an equation of motion with respect to time. On the other hand the acceleration is a function with respect to time and part of the equation of force (Newtons second law). I am a little bit confused now, so can anybody tell me if i have the right solution? If not, please tell me what i did wrong. I thank you all in advance for every kind of help for this solution.
 
Last edited:
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It looks good to me. Do they really ask for the equation of motion as a time-dependent equation? If they just said "Give an equation of motion explicitly of the form..." then I'm pretty sure you've done what they wanted you to do.
 

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