Mean value of energy <E> for a QM state?

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SUMMARY

The mean value of energy for the quantum state |ψ> = 1/sqrt(6) |v1> + 1/sqrt(3) |v2> - i/sqrt(2) |v3> is calculated using the Hamiltonian H|vj> = (2-j)a|vj>. The mean energy is determined to be -a/3, derived from the probabilities P = (1/6, 1/3, 1/2) and the corresponding eigenvalues. The root mean square deviation √( - ²) can be computed by evaluating using the same probabilities and eigenvalues without dividing by 2, as the state is properly normalized.

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Homework Statement


If the system is in a state

|ψ> = 1/sqrt(6) |v1> + 1/sqrt(3) |v2> - i/sqrt(2) |v3>

with Hamiltonian satisfying H|vj> = (2-j)a|vj>

Find the mean value of energy <E> and the root mean square deviation √(<E2> - <E>2 ) that would result from making a number of measurements of the energy of the system in state |ψ>

Homework Equations


<E> = <ψ|E|ψ>

for a free particle E = p2 / 2m

The Attempt at a Solution


[/B]
To find the mean value of Energy <E> is it just eigenvalues (a, 0 -a) multiplied by the probability of it being in the corresponding state P = (1/6, 1/3, 1/2)?

= a/6 - a/2 = -2a/6.
For E2 then do you just have the same, but the eigenvalues squared multiplied by the probabilities?
 
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except divide the energy by two? as its a mean, so it would be -a/6 ?
 
Why divide by 2 ? What would be the mean value for the identity operator 1 ?
 
BvU said:
Why divide by 2 ? What would be the mean value for the identity operator 1 ?
1, so do you just find the mean of the eigenvalues? So 0...
 
For the identity operator you get ##\ {1\over 6} + {1\over 3} + {(-i^*)(-i)\over 2} = 1 \ ##. No dividing by 2. The state is properly normalized.

For <H> you get ##\ {1\over 6} (a) + {1\over 3} (0) + {(-i^*)(-i)\over 2} (-a) = {\displaystyle -a\over 3} \ ## as you did. No dividing by 2 either.

So for <H2> ...
 

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