Measurement uncertainty: Standard uncertainty of the mean

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Homework Help Overview

The discussion revolves around the measurement uncertainty in X-ray analysis, specifically focusing on the standard uncertainty of the mean for the K-α line of copper. The original poster describes their process of obtaining the x-ray spectrum and fitting a Gaussian distribution to identify the K-α peak, leading to questions about the correct calculation of standard uncertainty.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the formula for standard uncertainty and question the correct interpretation of the variable N in the context of the original poster's data. There is a focus on clarifying whether N refers to the number of measurements or another value derived from the data.

Discussion Status

Participants are actively engaging in clarifying the formula for standard uncertainty and the meaning of N. There is a productive exchange of ideas, with some participants confirming the correct formula while others seek to ensure a mutual understanding of the variables involved.

Contextual Notes

The original poster references their lecture notes, indicating that there may be specific definitions or conventions from their coursework that are influencing their understanding of the problem.

garyd
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Homework Statement


Hi,

I am doing some basic X-ray analysis and trying to quantify the measurement uncertainty associated with my determined value for the K-α line of copper. I have obtained the x-ray spectrum from a copper target using a detector and multichannel analyzer (No. of pulses/pulse height as a function of energy in keV). I have identified and isolated the K-α peak. I have fitted a Gaussian/Normal distribution curve to the data, computed the mean value in keV and have computed the sample standard deviation. I now need to compute the standard uncertainty of the mean and I’m unsure of the correct method. As far as I know the standard uncertainty of the mean (u) is given by [1] below where N is the number of measurement readings taken in order to determine the mean value and sigma n-1 is the computed sample standard deviation.

Homework Equations



U=σn-1/N [1]

The Attempt at a Solution


The multi-channel analyzer effectively sorts and counts incident voltages of different magnitudes. I have an array of x-axis data in keV. e.g. x=[2 3 4 5 4 3 2] I am wondering is N the length of the array (=7) or the sum of the array (23)
 
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garyd said:
U=σn-1/N [1]
Shouldn't that be ##\sigma_{n-1}/\sqrt n##?
 
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haruspex said:
Shouldn't that be ##\sigma_{n-1}/\sqrt n##?
Yes it should be ##\sigma_{n-1}/\sqrt N##
But what value is N
 
garyd said:
Yes it should be ##\sigma_{n-1}/\sqrt N##
But what value is N
N is the number of values (which is why I wrote n; it's the same n as in σn−1).
 
Sorry i was referring to my lecture notes, n makes a lot more sense, thanks
 

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