Let t= x-1/2 so
[itex]\sqrt{x}= \sqrt{x-\frac{1}{2}+\frac{1}{2}}= \sqrt{t+\frac{1}{2}}=[/itex]
[itex]\frac{\sqrt{2}}{2} \sqrt{1+2t}[/itex]
and
[itex]e^{-x}= e^{-x+\frac{1}{2}-\frac{1}{2}}= e^{-t-\frac{1}{2}}= \frac{1}{\sqrt{e}}e^{-t}[/itex]
Observe that if [itex]x= \frac{1}{2}[/itex] then [itex]t=0[/itex], so you can use the MacLaurin expression:
[itex]\frac{\sqrt{2}}{2}\sqrt{1+2t}=\frac{\sqrt{2}}{2}+\frac{\sqrt{2}}{2} t-\frac{\sqrt{2}}{4}t^2+o(t^2)[/itex]
and
[itex]\frac{1}{\sqrt{e}}e^{-t}= \frac{1}{\sqrt{e}}-\frac{t}{\sqrt{e}}+\frac{t^2}{2\sqrt{e}}+o(t^2)[/itex]
(You have to remember the Maclaurin series of the functions:
[itex]e^{s}=1+s+\frac{s^2}{2}+...[/itex]
[itex]\sqrt{1+s}=1+\frac{s}{2}-\frac{s^2}{8}+...[/itex]
)
Now multiply:
[itex]\frac{\sqrt{2}}{2}\sqrt{1+2t}\frac{1}{\sqrt{e}}e^{-t}=\frac{1}{\sqrt{2 e}}-\frac{t^2}{\sqrt{2 e}}+o(t^2)[/itex]
but [itex]t= x-\frac{1}{2}[/itex] so
[itex]\frac{\sqrt{2}}{2}\sqrt{1+2\left(x-\frac{1}{2}\right)}\frac{1}{\sqrt{e}}e^{-(x-\frac{1}{2})}=\frac{1}{\sqrt{2 e}}-\frac{(x-\frac{1}{2})^2}{\sqrt{2 e}}+o((x-\frac{1}{2})^2)[/itex]