First I suggest you write a definition (adding it to this thread) what is a first order diffracted beam. After that, then define clearly in what second, third and higher order diffracted beams consist. Make sure these definitions are clearly presented and that they directly state necessary and sufficient conditions for each of the orders separately. Once the necessary and sufficient conditions for each order are clearly presented, then you can think whether and which any of the necessary conditions are missing for the 2nd, 3rd or any orders. That might make clear why the 2nd and 3rd orders "cannot occur" as in part "a)".
For part b) of your question, Consider that changing the voltage of the electron gun, changes the energy and momentum of the electrons. Use p=h/lambda but solve for lambda=h/p but write p as a function of voltage (you know that as voltage goes up so does p: figure out what the constant of proportionality is exactly, use the definition of 1 electron volt)
Thus using p=h/lambda, the de Broglie relation, any voltage change changes the wavelength of the electrons. Your equation provided in your number "2" is different from the one provided as the Bragg Law on the Wikipedia page for Davisson Germer:
https://en.wikipedia.org/wiki/Davisson–Germer_experiment
Changing the voltage from 54 to 60V should change the expected wavelength which in turn changes the angle according to that Bragg Law equation for n=1 on that Wikipedia page.
For your part "c)" set n=2 and theta=50 and solve for lambda but use the relation between wavelength and voltage from part b) above and you should answer this "c)" question
New question, part "d)" if 2nd order diffraction is forbidden as in part "a)" why is a 2nd order diffracted beam allowed in part "c)"?