No prefix: What is the energy required to ionize air?

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SUMMARY

The energy required to ionize air primarily involves breaking molecular bonds in nitrogen and oxygen, which constitute 99% of air. For 1 mol of air, consisting of 0.79 mol of N2 and 0.21 mol of O2, one must first break the triple bonds of nitrogen and the double bonds of oxygen. The necessary bond enthalpies can be found on WebElements, and the ionization energies for nitrogen and oxygen are detailed on Wikipedia. This process results in the formation of free atoms, which can then be ionized.

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  • Understanding of molecular bond enthalpies
  • Knowledge of ionization energies for nitrogen and oxygen
  • Familiarity with the composition of Earth's atmosphere
  • Basic chemistry concepts related to ionization
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  • Research bond enthalpies for nitrogen and oxygen on WebElements
  • Study ionization energies of nitrogen and oxygen on Wikipedia
  • Explore the process of molecular bond breaking in chemistry
  • Learn about the implications of ionization in atmospheric science
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Chemistry students, atmospheric scientists, and anyone interested in the energy dynamics of air ionization.

Alex Schaller
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Do you know which is the energy per mol required to ionize air? Once the air is ionized, does it recombine it´s charges so that after a while there is no ionized air at all? If this is the case, how long does it take for this to happen?
 
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Do you mean the VOLTAGE required for air break down? Or the energy required to remove a single electron from every atom in the mol?
 
I mean the energy required to remove a single electron from every atom in the mol.
 
I'm not sure whether or not this is homework, but this might be most appropriately answered in the Chemistry forum. Dredging up some of my high school chemistry, the process for ionization requires you to first break the molecular bonds (the triple bonds of nitrogen, and double bonds of oxygen) and form free atoms. Then, you need to ionize them.

Air is composed chiefly of nitrogen and oxygen (total 99%). I'd make a simplifying assumption and assume you have only nitrogen (79%) and oxygen (21%):
http://en.wikipedia.org/wiki/Earth's_atmosphere

Now, assume you have 1 mol of 'air' (0.79 mol of N2 and 0.21 mol of O2), figure out how much energy you need to break the bonds:
http://www.webelements.com/nitrogen/bond_enthalpies.html
http://www.webelements.com/oxygen/bond_enthalpies.html

Now figure out how much energy you need to ionize all these nitrogen and oxygen atoms (how many mols of each?)
http://en.wikipedia.org/wiki/Ionization_energies_of_the_elements

Presto! Amount of energy required to ionize air. Please show your work.
 
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