Normalization of a symmetric wavefunction

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phosgene
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Homework Statement



I need to find the normalization constant [itex]N_{S}[/itex] of a symmetric wavefunction

[itex]ψ(x_{1},x_{2}) = N_{S}[ψ_{a}(x_{1})ψ_{b}(x_{2}) + ψ_{a}(x_{2})ψ_{b}(x_{1})][/itex]

assuming that the normalization of the individual wavefunctions [itex]ψ_{a}(x_{1})ψ_{b}(x_{2}), ψ_{a}(x_{2})ψ_{b}(x_{1})[/itex] are both just 1 and not orthogonal.

Homework Equations



For a symmetric wavefunction [itex]ψ_{a}(x_{1})ψ_{b}(x_{2}) = ψ_{a}(x_{2})ψ_{b}(x_{1})[/itex]

3. Attempt at solution

I do the normalization and get [itex]N_{S}^2∫_{-∞}^{∞} 2 {|ψ_{a}(x_{1})ψ_{b}(x_{2})|}^{2} + ψ*_{a}(x_{1})ψ*_{b}(x_{2})ψ_{a}(x_{2})ψ_{b}(x_{1}) + ψ*_{a}(x_{2})ψ*_{b}(x_{1})ψ_{a}(x_{2})ψ_{b}(x_{1})dx_{1}dx_{2}=1[/itex]

Now, since the wavefunctions are symmetric, [itex]ψ*_{a}(x_{1})ψ*_{b}(x_{2})ψ_{a}(x_{2})ψ_{b}(x_{1}) = ψ*_{a}(x_{2})ψ*_{b}(x_{1})ψ_{a}(x_{2})ψ_{b}(x_{1})[/itex]

Since the answer is supposed to be [itex]N_{S}=1/\sqrt{2}[/itex], I'm guessing that [itex]ψ*_{a}(x_{1})ψ*_{b}(x_{2})ψ_{a}(x_{2})ψ_{b}(x_{1}) = 0[/itex], but I don't know why this would be.
 
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Well, you might have saved yourself some work by just applying the equality at the beginning, I think.

[itex]ψ(x_{1},x_{2}) = N_{S}[ψ_{a}(x_{1})ψ_{b}(x_{2}) + ψ_{a}(x_{2})ψ_{b}(x_{1})][/itex]
[itex]ψ_{a}(x_{1})ψ_{b}(x_{2}) = ψ_{a}(x_{2})ψ_{b}(x_{1})[/itex]
[itex]ψ(x_{1},x_{2}) = 2N_{S}ψ_{a}(x_{1})ψ_{b}(x_{2})[/itex]But in case you were wondering what to do with your later expression

[itex]\left(a^* + b^*\right)\left(a + b\right) = a^*a +b^*b + a^*b + ab^*[/itex]

[itex]= |a|^2 + |b|^2 + (a^*b) + (a^*b)^*[/itex]
Adding a number to its complex conjugate eliminates the imaginary component and doubles the real component.
[itex]= |a|^2 + |b|^2 + 2Re\left\{a^*b \right\}[/itex]

Consider what happens when [itex]a = b[/itex].

Edit: perhaps I'm missing something though
 
Last edited:
MisterX said:
Well, you might have saved yourself some work by just applying the equality at the beginning, I think.

[itex]ψ(x_{1},x_{2}) = N_{S}[ψ_{a}(x_{1})ψ_{b}(x_{2}) + ψ_{a}(x_{2})ψ_{b}(x_{1})][/itex]
[itex]ψ_{a}(x_{1})ψ_{b}(x_{2}) = ψ_{a}(x_{2})ψ_{b}(x_{1})[/itex]
[itex]ψ(x_{1},x_{2}) = 2N_{S}ψ_{a}(x_{1})ψ_{b}(x_{2})[/itex]

But if I do this and try to normalize it, won't I get

[itex]N_{S}^2∫_{-∞}^{∞}4|ψ_{a}(x_{1})ψ_{b}(x_{2})|^2 dx_{1}dx_{2}[/itex]

which gets me [itex]N_{S}=1/2[/itex]

MisterX said:
But in case you were wondering what to do with your later expression

[itex]\left(a^* + b^*\right)\left(a + b\right) = a^*a +b^*b + a^*b + ab^*[/itex]

[itex]= |a|^2 + |b|^2 + (a^*b) + (a^*b)^*[/itex]
Adding a number to its complex conjugate eliminates the imaginary component and doubles the real component.
[itex]= |a|^2 + |b|^2 + 2Re\left\{a^*b \right\}[/itex]

Consider what happens when [itex]a = b[/itex].

Edit: perhaps I'm missing something though

[itex]2Re(a*b) = 2|a|^2, 2|b|^2[/itex] and then overall I would get [itex]4|a|^2[/itex] or [itex]4|b|^2[/itex], which again gives me [itex]N_{S}=1/2[/itex], but I need [itex]N_{S} = 1/ \sqrt{2}[/itex] so I'm not really sure what to do
 
Perhaps I replied without sufficient knowledge. It might be that the number of states has been halved (identical particles).
 
phosgene said:
[itex]ψ(x_{1},x_{2}) = N_{S}[ψ_{a}(x_{1})ψ_{b}(x_{2}) + ψ_{a}(x_{2})ψ_{b}(x_{1})][/itex]

This is the wavefunction for two identical particles, specifically bosons. The wave function is required to satisfy the symmetry equation you stated. To solve, we have [itex]|N_{S}|^2∫[ψ_{a}(x_{1})ψ_{b}(x_{2}) + ψ_{a}(x_{2})ψ_{b}(x_{1})]^{*}[ψ_{a}(x_{1})ψ_{b}(x_{2}) + ψ_{a}(x_{2})ψ_{b}(x_{1})]dx_{1}dx_{2}=1[/itex]. Expand this equation out carefully. It is always possible to orthonormalize using Gram-Schmidt so that [itex]∫|ψ_{a}(x_{1})^2|=1[/itex] and [itex]∫ψ_{a}(x_{1})^{*}ψ_{b}(x_{1})=0[/itex]. This should give you [itex]N_{S} = 1/√2[/itex].