Optimizing Ammonia Production: Calculating Partial Pressures and Reactant Ratios

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SUMMARY

The discussion focuses on optimizing ammonia production by calculating partial pressures and reactant ratios in an ammonia plant operating at approximately 700K with a Kp of 3.5 x 10-4. The current stoichiometric ratio of nitrogen to hydrogen (N2:H2) is 1:3, with an equilibrium partial pressure of ammonia (NH3) at 50 atm. A proposal suggests altering the reactant ratio to 1:6 to maintain ammonia production at lower pressure, potentially increasing profitability. The validity of this suggestion hinges on calculating the new partial pressures of the reactants and total pressure under the proposed conditions.

PREREQUISITES
  • Understanding of chemical equilibrium and reaction quotients
  • Familiarity with the ideal gas law and partial pressure calculations
  • Knowledge of stoichiometric ratios in chemical reactions
  • Basic principles of profitability analysis in chemical production
NEXT STEPS
  • Calculate the partial pressures of N2 and H2 using the new 1:6 ratio
  • Explore the implications of changing reactant ratios on equilibrium constants
  • Investigate the economic factors influencing reactant costs in ammonia production
  • Learn about the impact of temperature on chemical equilibrium and reaction rates
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Chemical engineers, process optimization specialists, and anyone involved in ammonia production or chemical manufacturing profitability analysis.

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An ammonia plant operates at close to 700K and a Kp of 3.5 x 10-4 employing the stoichiometric ratio of 1:3 N2:H2. If the equilibrium partial pressure of NH3 is 50. atm, calculate the partial pressures of the reactants and the total pressure.
The suggestion is made that, since the [NH3] is cubed in the reaction quotient, the plant could produce the same amount of ammonia if the reactant ratio were 1:6 - and at a lower pressure and increased profitability. Calculate the partial pressure of each reactant and the total pressure under these new conditions assuming PNH3 is still 50. atm at equilibrium.
Is the suggestion valid?


Since when is NH3 cubed?
What do we have to do? I don't understand anything. What is the 1:6 ratio? How do we prove improved profitability?
 
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I agree, cubed seems wrong.
 
yolo123 said:
An ammonia plant operates at close to 700K and a Kp of 3.5 x 10-4 employing the stoichiometric ratio of 1:3 N2:H2. If the equilibrium partial pressure of NH3 is 50. atm, calculate the partial pressures of the reactants and the total pressure.
The suggestion is made that, since the [NH3] is cubed in the reaction quotient, the plant could produce the same amount of ammonia if the reactant ratio were 1:6 - and at a lower pressure and increased profitability. Calculate the partial pressure of each reactant and the total pressure under these new conditions assuming PNH3 is still 50. atm at equilibrium.
Is the suggestion valid?


Since when is NH3 cubed?
What do we have to do? I don't understand anything. What is the 1:6 ratio? How do we prove improved profitability?

From context the the 1:6 ratio should be the N2:H2 ratio, which previously was 1:3.

I'd suggest you first try to answer the understandable and solvable questions.

When answers are evaluated by humans not computers you should normally get credit if you state the question you think you are answering and give an intelligent answer.

What is more economical could depend on the relative costs of the two reactants, or it might be independent, hard to say beforehand. You need to write some equations and attempt some calculations first.
 

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