Oxidation of cyclohexanol to hexane-1,6 dioic acid?

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SUMMARY

The oxidation of cyclohexanol to hexane-1,6-dioic acid can be achieved using concentrated nitric acid (HNO3) instead of sulfuric acid (H2SO4). Cyclohexanol, a secondary alcohol, undergoes dehydration to form cyclohexene before being oxidized to the carboxylic acid. This process, while not commonly stated in textbooks, is confirmed by visual references shared in the discussion. The use of HNO3 for this oxidation reaction is a valid alternative to H2SO4.

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Homework Statement



is it possible to use conc HNO3 instead of H2SO4 to allow the reaction of oxidation of cyclohexanol to haxane-1.6 dioic acid to occur?

how can the reaction occur? cyclohexanol is seconary alcohol , it should be oxidised to ketone am i right? but it's oxidised to carboxylic acid...

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The Attempt at a Solution



i was told that cyclohexanol is dehydrated to cyclohexene first , then it only oxidised to haxane-1,6 dioic acid... but it's not stated in the book... is the statement above correct? [/B]
 

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somecelxis said:
is it possible to use conc HNO3 instead of H2SO4 to allow the reaction of oxidation of cyclohexanol

That's the way it is done. It is on the image you posted. I guess you meant something else.
 
Borek said:
That's the way it is done. It is on the image you posted. I guess you meant something else.
In my book, the oxidation process is carried out using the conc h2s04 ... For alcohol.. This is the first time I saw it with conc hno3...
 

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