Parity - Particle In A Box (Infinite Potential)

Join the discussion
Registration is free. Ask a follow-up in this thread, or start your own.
1 reply · 5K views
catinabox
Messages
1
Reaction score
0
I am trying to work out the wavefunctions for a particle in a box between -a/2 and a/2.I have already gone through the solution for a box between 0 and a and got the solution [tex]\sqrt{\frac{2}{a}}sin(\frac{n\pi x}{a} )[/tex]So I can see that for -a/2 to a/2 I have [tex]\sqrt{\frac{2}{a}}sin(\frac{n\pi(x+\frac{a}{2})}{a})[/tex]Which by some trig leads to [tex]\sqrt{\frac{2}{a}}sin(\frac{n\pi x}{a})cos(\frac{n\pi}{2})+\sqrt{\frac{2}{a}}cos(\frac{n\pi x}{a})sin(\frac{n\pi}{2})[/tex]Now i can see it differs for even and odd n as for even n [tex]sin(\frac{n\pi}{2})=0[/tex] for odd n [tex]cos(\frac{n\pi}{2})=0[/tex].

(NOT SURE WHATS HAPPENED WITH LATEX HERE :()Therefore even n leads to [tex]\sqrt{\frac{2}{a}}sin(\frac{n\pi x}{a})cos(\frac{n\pi}{2})[/tex] odd n leads to [tex]\sqrt{\frac{2}{a}}cos(\frac{n\pi x}{a})sin(\frac{n\pi}{2})[/tex]From research I have found that the wavefunction for n even is in fact just [tex]\sqrt{\frac{2}{a}}sin(\frac{n\pi x}{a})[/tex] and odd n just [tex]\sqrt{\frac{2}{a}}cos(\frac{n\pi x}{a})[/tex]This is were I am confused because the [tex]cos(\frac{n\pi}{2})[/tex] for even n is positive or negative 1 and [tex]sin(\frac{n\pi}{2})[/tex] for odd n is positive or negative 1.Why is only the positive chosen, is this to do with normalistion?Any help is much appreciated.Thank you.
 
Last edited:
Physics news on Phys.org
n only has physical meaning for positive values because if you evaluate the energy eigenfunctions, you find that

[tex]E_n = \frac{n^2 \pi^2 \hbar^2}{2ma^2}[/tex]

Mathematically, at least, it is unnecessary for n to be less than 0. Going by this equation, E0 is by definition the lowest possible energy state, or ground state.