Parity switching wave functions for a parity invariant hamiltonian?

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SUMMARY

The discussion centers on the concept of parity in quantum mechanics, specifically regarding the variational method for approximating wave functions and energy levels in systems with even potentials, such as V(x) = λx^4. It is established that for a parity invariant Hamiltonian, the eigenstates exhibit alternating parity, a principle supported by examples from the harmonic oscillator and infinite square well. The mathematical reasoning behind this phenomenon is linked to the number of nodes in the eigenfunctions, where each eigenfunction's parity corresponds to the parity of the number of nodes it possesses.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly wave functions and energy levels.
  • Familiarity with the variational method in quantum mechanics.
  • Knowledge of parity invariance in Hamiltonians.
  • Basic concepts of eigenstates and nodes in quantum systems.
NEXT STEPS
  • Study the variational method in quantum mechanics using Shankar's "Principles of Quantum Mechanics".
  • Explore the harmonic oscillator model and its eigenstates in detail.
  • Investigate the properties of parity in quantum systems, focusing on even and odd potentials.
  • Review Messiah's "Quantum Mechanics" for insights on the number of nodes in bound states.
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Students and professionals in quantum mechanics, physicists exploring wave functions and energy levels, and anyone interested in the implications of parity in quantum systems.

VortexLattice
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Hi guys, I'm reading Shankar and he's talking about the Variational method for approximating wave functions and energy levels.

At one point he's using the example [itex]V(x) = λx^4[/itex], which is obviously an even function. He says "because H is parity invariant, the states will occur with alternating parity".

I believe him because I remember this from the Harmonic oscillator and the infinite square well, and I see why in each of those examples they alternate, from a mathematical standpoint.

But is there a better physical explanation? Right now all I can really tell is, mathematically, for those two examples, the solutions have to have alternating parity. So how can he say this for sure of all even potentials?

Thanks!
 
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Anyone? I'm very curious.
 
See Messiah, Vol I, Chapter III, "One-Dimensional Quantized Systems", Sect 12, "Number of Nodes of Bound States". If one arranges the eigenstates oin the order of increasing energies, the eigenfunctions likewise fall in the order of increasing number of nodes; the nth eigenfunction has (n-1) nodes between each of which the following eigenfunctions all have at least one node.

Regarding parity, each eigenfunction is either even or odd. If you have an even/odd number of nodes, you must have an even/odd eigenfunction.
 

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