Partial Pressure Calculation for Oxygen in a Closed Container

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SUMMARY

The discussion centers on calculating the volume of dry oxygen gas in a closed container using the principles of gas laws. The initial conditions include a 172 mL container at 15°C with a barometric pressure of 754 torr, and the water's partial pressure at this temperature is 12.8 torr. The correct approach involves subtracting the water's partial pressure from the total pressure to find the dry gas pressure, leading to the calculation of the new volume at 778 torr, resulting in a final volume of approximately 166.78 mL.

PREREQUISITES
  • Understanding of gas laws, specifically Boyle's Law
  • Knowledge of partial pressure calculations
  • Familiarity with the concept of wet and dry gas measurements
  • Basic skills in unit conversion and manipulation of equations
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  • Study Boyle's Law and its applications in gas volume calculations
  • Learn about the concept of partial pressures in gas mixtures
  • Research the effects of temperature on gas behavior using the Ideal Gas Law
  • Explore practical applications of gas laws in laboratory settings
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Chemistry students, laboratory technicians, and anyone involved in gas measurement and calculations in closed systems.

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1) Question:
A sample of oxygen is collected in a 172 mL
container over water at 15C, and the barom-
eter reads 754 torr. What volume would the
dry gas occupy at 778 torr and 15C? Water's
partial pressure at 15C is 12:8 torr. Answer
in units of mL.
2)attempt to answer:
pv=PV
temp constant
(754+12.8)*172=(778+12.8)V
V=166.779969
I'm not exactly sure if this is the right way to do it since the question's wording is a bit confusing and there seems to be some useless information. Can anyone tell me if my answer is right here?
Thanks
 
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you need to SUBTRACT the partial pressure of water from the first pressure of 754 torr. (wet gas to dry gas) This is now p1, v1 = initial volume. P2 is the new pressure 778. find V2
 
thanks! i understand now!
 

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