Particle in a potential- variation method

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Homework Help Overview

The discussion revolves around the variational method applied to a quantum mechanics problem involving a particle in a potential defined by \( V(x) = V_0 \frac{|x|}{a} \). Participants are tasked with sketching the ground state wave function and determining an approximate value for the ground state energy using various trial functions.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the characteristics that make a trial function appropriate, such as normalizability and the presence of nodes. There is also mention of the need to minimize the expectation value of the Hamiltonian with respect to a variational parameter.

Discussion Status

Some participants have provided guidance on the normalization of wave functions and the general shape expected for the ground state wave function. There are ongoing explorations of different trial functions, with suggestions to compare results from multiple functions. However, there is no explicit consensus on the best approach or function to use.

Contextual Notes

Participants note potential confusion regarding the trial functions listed, with some functions being identified as similar or inappropriate. There is also a reference to the complexity of solving the integral associated with the variational method.

Rorshach
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Homework Statement


Okay, I have no idea about the method they want me to solve it with. What in this case is the indicator that a function is appropriate?
A particle mass m affects a potential of the form ##V(x)=V_0 \frac{|x|}{a}## where ##V_0## and ##a## are positive constants.

a) Draw a sketch of the ground state wave function and indicate the characteristics of this function.

b) Use the variation method to determine an approximate value of the ground state energy. Use functions selected from the list below. Some of these functions are unsuitable while others are less good. Give reasons for all if they are worse or better! Then do the calculation with the function that you find most suitable.

##Nsin(\alpha x)exp(-\alpha |x|)##
##Nexp(-\alpha x^2)##
##\frac{N}{(x^2+\alpha^2)}##
##Nexp(-\alpha x^2)##
##\frac{N}{\sqrt{|x|+\alpha}}##


Homework Equations





The Attempt at a Solution



 
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You've never learned about the variational method? Just look it up.

In quantum I don't think there was any way to choose an "appropriate" trial function, but with a given trial function you just normalize it and then minimize the expectation value of the Hamiltonian with respect to the variational parameter (alpha).
 
Rorshach said:
What in this case is the indicator that a function is appropriate?


The wavefunction should be normalizable, for example. Should the ground state have any "nodes" (places where ψ = 0 other than at infinity)?

Your 2nd and 4th wavefunctions look identical to me.

For a rough sketch of the ground state, note that your potential is very roughly like a harmonic oscillator potential. So, roughly, you can expect a graph of the ground state wavefunction to have the general appearance of the ground state of the harmonic oscillator.
 
The ground state should be flat, without any nodes, right? You are right, the second function was supposed to be ##Nxexp(-\alpha x^2)## I decided that fourth function is the one I should use, so I normalized it and the constant is equal to ##N=\sqrt[4]{\frac{2}{\pi}\alpha}##. The next thing according to the book is the equation that looks more or less like this: ##\int_{-\infty}^{+\infty} exp(-2\alpha x^2)(-\frac{2\hbar^2 \alpha^2 x^2}{m}+\frac{\hbar^2 \alpha}{2m}+V_0 \frac{|x|}{\alpha}) \,dx##
http://www.wolframalpha.com/input/?...|x|/a))),[x,-inf,+inf]&a=*C.V-_*RomanNumeral-
But I have a problem with solving this integral. How should it look like?
 
Last edited:
you have to setup a variation integral for the energy and then minimize it with respect to alpha to get alpha.Then you will have wave function and energy both.
 
Rorshach said:
The ground state should be flat, without any nodes, right? You are right, the second function was supposed to be ##Nxexp(-\alpha x^2)## I decided that fourth function is the one I should use, ...

I haven't worked it out, but why not also investigate the third function and compare with result for fourth function?
 

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