Particle subject to a hopping potential between two atoms in a lattice

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Homework Help Overview

The discussion revolves around a particle subject to a hopping potential Hamiltonian between two atoms in a lattice, modeled as a discrete 2-state system. The original poster expresses uncertainty about the relevant equations and the approach to determine the particle's evolution over time.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster considers using statistical arguments and the Hubbard model but questions their applicability to the problem. They also contemplate modeling the situation with two Hydrogen atoms sharing one electron.

Discussion Status

Some participants suggest relating the problem to Feynman's Lectures on Physics, specifically the treatment of the ammonia molecule, which seems to resonate with the original poster's inquiry. This indicates a productive direction in the discussion.

Contextual Notes

The original poster notes that the problem is for a general particle and not specific to fermions or bosons, which influences their approach to the solution.

Trance
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Hello! Long time lurker, first time poster. This is the first of a couple of questions which has totally stumped me, although I have a feeling it's easier than it first seems.

Homework Statement


A particle is initially located at one of two atoms. The particle is subject to Hhop ,
a discrete hopping potential Hamiltonian between the two atoms, whose strength
is constant in time. Model the particle’s location as a discrete 2-state system, and
determine the evolution as a function of time


Homework Equations


This is what's getting me - I'm not entirely sure what the relevant equations are! I believe a Hopping potential describes the likelyhood of the particle 'hopping' to the adjacent atom, but I'm not 100% sure about that.


The Attempt at a Solution



At first I thought to use statistical arguments, but these fail of course, because there is only one particle. The question is also for a general particle, not a specific fermion/boson, so I doubt that's the way to go. I've thought about using the Hubbard model, but from my research (We haven't explicitly studied it in my degree yet), it seems more relevant to electrons in an atom rather than particles in a lattice. I had the thought to perhaps model the situation as two Hydrogen atoms, sharing one electron, and then use the Hubbard model, but think this could be a little too specific.

Any help would be greatly appreciated!
 
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Hello trance.

Do you have access to Feynman's Lectures on Physics? If so, you might find it interesting to relate your problem to his treatment of the ammonia molecule in chapter 8 of volume III.
 
TSny said:
Hello trance.

Do you have access to Feynman's Lectures on Physics? If so, you might find it interesting to relate your problem to his treatment of the ammonia molecule in chapter 8 of volume III.
TSny, that is a fantastic catch. Thank you so much! This describes almost exactly what I was looking for.
 
Ah, Good! I was hoping (hopping) so. Feynman has a very nice discussion.
 

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