SUMMARY
The discussion centers on the eigenvalues of the Pauli spin operator for a two-electron system, specifically addressing a discrepancy in the answer key regarding the eigenvalue of σ². Participants clarify that the correct eigenvalue is given by the formula ℏ²s(s+1), where s represents the total spin. The confusion arises from a misinterpretation of the eigenvalue as 4s(s+1), which is confirmed to be incorrect. The Hamiltonian for the system includes interactions described by the Pauli matrices and an applied magnetic field affecting only one spin.
PREREQUISITES
- Understanding of quantum mechanics, specifically spin systems.
- Familiarity with Pauli matrices and their applications in quantum mechanics.
- Knowledge of Hamiltonians and their role in quantum systems.
- Basic grasp of eigenvalues and eigenfunctions in quantum mechanics.
NEXT STEPS
- Study the derivation of eigenvalues for the Pauli spin operator using the formula ℏ²s(s+1).
- Explore the implications of the Hamiltonian Hex = A~σ1 · ~σ2 in two-electron systems.
- Investigate the effects of the Zeeman Hamiltonian HZ = gµBB~ · ~σ1 on spin states.
- Review Sakurai's "Modern Quantum Mechanics" for a deeper understanding of spin systems and eigenvalue problems.
USEFUL FOR
Quantum mechanics students, physicists specializing in spin systems, and researchers working on quantum information or magnetic interactions in multi-electron systems will benefit from this discussion.