Physical reason for diagonal matrix

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SUMMARY

The discussion centers on the physical significance of diagonalized matrices in quantum mechanics (QM) and classical mechanics (CM), particularly regarding eigenvalues and eigenfunctions. It is established that in QM, the eigenvalues of a Hermitian operator represent the possible outcomes of a measurement, and the wavefunction can be expressed as a linear combination of these eigenfunctions. The expectation value of an observable is derived from these eigenvalues, reinforcing the importance of diagonalization in simplifying complex systems. In CM, diagonalization aids in solving coupled oscillator systems by transforming the equations into independent coordinates, highlighting the utility of linear algebra across physics.

PREREQUISITES
  • Understanding of eigenvalues and eigenvectors in linear algebra
  • Familiarity with Hermitian operators in quantum mechanics
  • Knowledge of the Schrödinger Equation and its implications
  • Basic concepts of classical mechanics, particularly coupled oscillators
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  • Study the properties of Hermitian operators in quantum mechanics
  • Learn about the diagonalization process of matrices in linear algebra
  • Explore the application of eigenvalues in solving differential equations in classical mechanics
  • Investigate the role of expectation values in quantum measurements
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Students and professionals in physics, particularly those focusing on quantum mechanics and classical mechanics, as well as mathematicians interested in the applications of linear algebra in physical systems.

Brewer
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Whats the physical reason for a diagonalized matrix with the eigenvalues of the system as the values?

Reading from wiki, it seems that its something to do with the Schrödinger Eqn, but I don't follow that. If someone could explain the point of it to me in plain English (or as close as it gets!) then I'd be very grateful to them.
 
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Can you be a little more specific? Are you talking about quantum mechanics, where a measurement of a Hermitian operator will always give an eigenvalue of the operator?
 
Sorry, yes I am. I didn't realize there was a difference.
 
If you have Griffith's book on QM, it is explained quite clearly in chapter 3; to be more precise in section 3.2. The argument is roughly as follows:
  • Recall that the expectation value of an observable A, for a system described by wavefunction \Psi is
    \langle A \rangle = \int \Psi^* \hat A \Psi \, \mathrm dx
  • We want the outcome of a measurement to be real, so in particular we want the expectation value (~ average) to be real:
    \langle A \rangle = \langle A \rangle^*
  • It is now easy to see that this must lead to the property of A being Hermitian.
  • If the system is in a determinate state (a state in which a measurement of A yields a well-defined value; for example stationary states are determinate states of the Hamiltonian) then you want the standard deviation
    \langle \hat A - \langle A \rangle )^2 \rangle
    to vanish. This can be shown to lead to
    \hat A \Psi = \lambda \Psi
    for some number lambda. In other words, determinate states are eigenfunctions of \hat A.
  • The eigenfunctions of a Hermitian operator can be shown to be orthogonal (or, in case of multiple eigenfunctions for the same eigenvalue, we can choose them to be such). Moreover, the wave-function can be decomposed into the eigenfunctions f_n of \hat A, meaning we can write
    \Psi = \sum_n c_n f_n with c_n = \int f_n(x)^* \Psi(x, t) \, \mathrm dx
    (in the discrete case, replace the sum by an integral in the continuum case)
  • Now using all these properties, you can show that
    \langle A \rangle = \sum_n \lambda_n |c_n|^2
    where \lambda_n are the eigenvalues \hat A f_n = \lambda_n f_n. This is precisely the expectation value for an experiment where the outcome \lambda_n has probability |c_n|^2!

To summarize then: the possible outcomes of a measurement of an observable are the eigenvalues of that observable. This means that we have to calculate the eigenvalues, which you know how to do in the finite case from linear algebra (you can write \hat A as a matrix). Usually, if you're going to work with A (dropping the hat from now on) a lot in your particular problem, it might pay off to express everything in eigenstates of A. From linear algebra you know, that this is equivalent to diagonalizing A such that the eigenvalues are explicit in the way you write it down.

Hope that clarifies.
 
Brewer said:
I didn't realize there was a difference.
You can do the same thing in classical mechanics. The typical example studied is that of a system of coupled oscillators. You can write the Lagrangian in terms of the displacements of the individual oscillators as the generalized coordinates, but you will find that the differential equations can be quite difficult to solve, because they mix the coordinates. You will find that it is much easier to solve the system if you discover some clever generalized coordinates that can be treated independently, so that you obtain a set of differential equations that each involve a single coordinate. This can be done by diagonalizing a matrix, and the characteristic frequencies are the eigenvalues.
 
In fact, in any part of physics where linear algebra occurs (and since we like to work with linear things because they are so simple, it occurs almost everywhere - either exactly, or in approximation) you can play such tricks. For then you can work with eigenvalues and eigenvectors, which means diagonalizing the matrix, and in the end you can just take linear combinations afterwards to describe the whole system.
 
Brewer said:
Whats the physical reason for a diagonalized matrix with the eigenvalues of the system as the values?

Reading from wiki, it seems that its something to do with the Schrödinger Eqn, but I don't follow that. If someone could explain the point of it to me in plain English (or as close as it gets!) then I'd be very grateful to them.

There's a short, generally applicable answer too, but not real physical.

The diagonalised matrix is a change of basis, where all vector quantities undergo dilation or contraction.

Edit: I think that was unclear. We cn represent the matrix in a different coordinate system. In the coordinate system where the matrix is in diagonal form all vector quantities operated upon by the diagonalized matix undergo dilation or contraction.
 
Last edited:
But Brewer should be aware of the profound physical difference in the interpretation of this mathematics in QM vs. CM. In CM, the interpretation is basically as Phrak suggests, and then one must further interpret what is the meaning of such vector stretching. In QM, the interpretation is completely different, because a stretched version of a state vector is interpretted as the same state, and so the eigenvalues have no effect on the state, but rather the possible results of the measurement. In fact, instead of stretching the vector, in QM the vector is rotated but maintains its length.
 

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