Planar Concentration of Nb Atoms in BCC Crystal

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SUMMARY

The discussion focuses on calculating the planar concentrations of niobium (Nb) atoms in a body-centered cubic (BCC) crystal structure with a lattice parameter of a = 0.3294 nm. The planar concentrations for the (100), (110), and (111) planes are derived, with the (100) plane containing 1 atom, the (110) plane containing 2 atoms, and the (111) plane requiring a detailed geometric analysis using the Pythagorean theorem. The calculations confirm that the (111) plane does not pass through the center atom in the BCC structure, contrasting with the face-centered cubic (FCC) model where the (111) plane intersects an atom.

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  • Understanding of BCC and FCC crystal structures
  • Familiarity with planar density calculations
  • Proficiency in using the Pythagorean theorem for geometric problems
  • Knowledge of lattice parameters and atomic arrangements
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Homework Statement


Niobium Nb has the BCC crystal with a lattice parameter of a= .3294 nm

Find the planar concentrations of atoms per m^2 of the (100, (110) and (111) planes.

The 100 plane has 1 atom on the plane (1/4 times 4)

the 110 plane has 2 atoms on the plane and using pythagorean theorem the long side is a*sqrt(2)

http://www.gly.uga.edu/schroeder/geol6550/111.jpeg
best pic I could find for the 111 plane
Now for the last plane (111) this is what I did

the area would be 1/2 base * height
the base is a*\sqrt2 and

pythagorean theorem to find the height is a^2 and half of the long side from plane (110) squared \sqrt{a^2+\frac{2a^2}4}=.4034nm

<br /> \frac12(.4034)10^{-9}(.3294)10^{-9}<br />
Now how many atoms are on the plane? and are there mistakes in what I have done so far?

And how many atoms would that (111) plane have in a FCC model?
Answer would have number of atoms over area
Thanks for the help
 
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One should find diagrams and discussion in W.D. Callister, Materials Science and Engineering, An Introduction, 7th Ed., John Wiley and Sons, 2007, or later editions.

Problems with planar densities of fcc and bcc are found in this assignment.
http://maecourses.ucsd.edu/~jmckittr/mae20-wi11//Assignment 4 solutions.pdf

One calculates the number of atoms per unit area, where area may be given in terms of nm2.

For the (111) plane in bcc, note that the plane does not pass through the atom in the center of the cubic structure. The base is the diagonal in one of the 6 faces, so the length is as one shows, ##\sqrt{2}##a.

The height of the triangle (hypotenuse) formed by the base of the (111) plane to the upper corner of the cell is found from the Pythagorean theorem, realizing one measures from the center of the diagonal to the upper corner of the cubic cell. One's answer is correct.

For an fcc cell, note that the base of the (111) plane (the diagonal of the unit cell) does intersect an atom.
 

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