Probability density for the hydrogen atom

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SUMMARY

The discussion centers on the calculation of the probability density for the hydrogen atom's wave function, specifically addressing the superposition of states. Participants clarify that the correct expression for the modulus squared of the wave function is given by $$|\psi|^2 = |\psi_1|^2 + |\psi_2|^2 + \psi_1\psi_2^* + \psi_2 \psi_1^*$$, emphasizing the importance of normalization. The conversation also highlights that the wave functions involved are real-valued and discusses the challenges of visualizing the resulting probability density in the xy-plane.

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  • Understanding of quantum mechanics concepts, particularly wave functions
  • Familiarity with the hydrogen atom model and its quantum states
  • Knowledge of probability density and normalization in quantum mechanics
  • Basic skills in mathematical notation and complex numbers
NEXT STEPS
  • Study the normalization of wave functions in quantum mechanics
  • Explore the concept of superposition in quantum states
  • Learn about probability density functions in quantum mechanics
  • Investigate graphical representations of wave functions in the xy-plane
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Students of quantum mechanics, physicists working with atomic models, and anyone interested in the mathematical foundations of wave functions and probability densities.

wakaranai
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Homework Statement
Consider a superposition state |Ψ⟩ = (|2, 0, 0⟩ + |2, 1, 0⟩) of the hydrogen atom.
a) Calculate the probability density at t = 0 and sketch the function in the (xy) plane.
b) Calculate ⟨Ψ|r|Ψ⟩ and mark on the graph the expected value of the position obtained in part (a). Interpret your result.
Relevant Equations
I'm not certain about the equations
I did this and I don't know if it's correct:
prob.jpeg
 
Last edited:
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:welcome:

Please see the guidelines for asking for homework help:

https://www.physicsforums.com/threads/homework-help-guidelines-for-students-and-helpers.635513/

Here are some common mistakes to avoid:
  • Don't simply say "I have no clue," "I have no idea where to start," or "I'm completely lost."
    These don't qualify as attempts. Instead, it suggests you haven't put much effort into reading and understanding your textbook and lecture notes, going over similar examples, etc. The helpers aren't here to answer your questions so that you don't have to read your book. We get that some people say this even though they've put in the effort. If this is you, please heed the next bit of advice.
 
PeroK said:
:welcome:

Please see the guidelines for asking for homework help:

https://www.physicsforums.com/threads/homework-help-guidelines-for-students-and-helpers.635513/

Here are some common mistakes to avoid:
  • Don't simply say "I have no clue," "I have no idea where to start," or "I'm completely lost."
    These don't qualify as attempts. Instead, it suggests you haven't put much effort into reading and understanding your textbook and lecture notes, going over similar examples, etc. The helpers aren't here to answer your questions so that you don't have to read your book. We get that some people say this even though they've put in the effort. If this is you, please heed the next bit of advice.
So sorry, now i tried to include my attempt.
(English is not my first language)
 
wakaranai said:
So sorry, now i tried to include my attempt.
(English is not my first language)
If ##\psi = \psi_1 + \psi_2##. Which of these is correct?
$$|\psi|^2 = |\psi_1|^2 + |\psi_2|^2$$$$|\psi|^2 = (\psi_1 + \psi_2)(\psi_1^* + \psi_2^*) = |\psi_1|^2 + |\psi_2|^2 + \psi_1\psi_2^* + \psi_2 \psi_1^* $$
 
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PeroK said:
If ##\psi = \psi_1 + \psi_2##. Which of these is correct?
$$|\psi|^2 = |\psi_1|^2 + |\psi_2|^2$$$$|\psi|^2 = (\psi_1 + \psi_2)(\psi_1^* + \psi_2^*) = |\psi_1|^2 + |\psi_2|^2 + \psi_1\psi_2^* + \psi_2 \psi_1^* $$
the second one...
in this case ψ_1=ψ*_1 (and the same for ψ_2)?
 
wakaranai said:
the second one...
in this case ψ_1=ψ*_1 (and the same for ψ_2)?
Yes, those particular wave functions are real-valued.

Note also that the wave-function you have been given is not normalised:
wakaranai said:
Consider a superposition state |Ψ⟩ = (|2, 0, 0⟩ + |2, 1, 0⟩) of the hydrogen atom.
That wavefunction has a modulus squared of ##2##. I would have expected:
$$\ket \psi = \frac 1 {\sqrt 2}\big (\ket {2,0,0} + \ket {2,1,0} \big )$$
 
PeroK said:
Yes, those particular wave functions are real-valued.

Note also that the wave-function you have been given is not normalised:

That wavefunction has a modulus squared of ##2##. I would have expected:
$$\ket \psi = \frac 1 {\sqrt 2}\big (\ket {2,0,0} + \ket {2,1,0} \big )$$
prob2.jpeg


I don't know how to relate the result with the plot in xy plane
 
wakaranai said:
View attachment 330311

I don't know how to relate the result with the plot in xy plane
You seem to have got a lot of simplification for your final answer. Are you sure about that? I would expect the result to be messy.

Note that, in the x-y plane, we have ##\cos \theta = 0##. That should simplify things. Even so, sketching that function wouldn't be easy!
 
PeroK said:
You seem to have got a lot of simplification for your final answer. Are you sure about that? I would expect the result to be messy.

Note that, in the x-y plane, we have ##\cos \theta = 0##. That should simplify things. Even so, sketching that function wouldn't be easy!
So |Ψ|^2 = |Ψ_1|^2
 
  • #10
wakaranai said:
So |Ψ|^2 = |Ψ_1|^2
Looks like it.
 

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