Problem on perturbation theory

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SUMMARY

The discussion focuses on calculating the ground state energy of a helium-like atom using first-order perturbation theory, specifically addressing the electron-electron interaction. The participants emphasize the importance of treating the term k/(r12)² as a perturbation to simplify the Hamiltonian. The integral provided, ∫dτ1∫dτ2 e^-(r1+r2)/r1+r2 = 20π², serves as a key equation in the analysis. Participants seek clarification on the perturbing and unperturbed Hamiltonians and the eigenfunctions of the unperturbed Hamiltonian.

PREREQUISITES
  • Understanding of first-order perturbation theory
  • Familiarity with Hamiltonian mechanics
  • Knowledge of quantum mechanics, particularly in multi-electron systems
  • Proficiency in LaTeX for mathematical expressions
NEXT STEPS
  • Study the derivation of the unperturbed Hamiltonian for helium-like atoms
  • Learn about the application of first-order perturbation theory in quantum mechanics
  • Explore the mathematical treatment of electron-electron interactions in quantum systems
  • Practice writing LaTeX for complex equations in quantum mechanics
USEFUL FOR

Students and researchers in quantum mechanics, particularly those focusing on atomic physics and perturbation theory, will benefit from this discussion.

sridhar
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Homework Statement


Determine approximately the ground state energy of a helium like atom using first order perturbation theory in the electron-electron interaction.
Ignore the spins of the electrons and the Pauli principle.


Homework Equations


given that \intd\tau1\intd\tau2 e^-(r1+r2){}/r1+r2 = 20\Pi^{2}

The Attempt at a Solution


Consider a system where electron1-electron2 distance = r12
electron1-nucleus distance= r1
electron2-nucleus distance= r2

The S.E of this system would be exactly solvable if the term containing r12 disappears from the hamiltonian. Therefore we treat k/(r12)^{2} as the perturbation!

I applied the first order perturbation for the term k/r12
the correction would basically be <\Psi /k/(r12)^{2} / \Psi>

And i am stuck! Cant understand what to do next!
 
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Can you write down the perturbing and unperturbed hamiltonia, and the eigenfunctions of the unperturbed hamiltonian?

Why are you squaring r12?

PS: When writing down an expression/equation, it is best to LaTeX the whole thing (Example: \langle \psi | (k/r_{12})| \psi \rangle), rather than parts of it. Also, for using LaTeX in line with regular text, use the tags [ itex ] [ /itex ] (without spaces) instead.
 

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