If a tensor T is rotationally invariant, that means that for every rotation R, that T = RT.T.R. Note that RT = R-1.
Since pure rotations form a Lie group, we can use its Lie algebra: R = 1 + ε*L for small ε. Since LT = -L, that gives us commutator [L,T] = 0.
A rotation-algebra generator has form (Lab)ij = δaiδbj - δajδbi to within some multiplicative factor. Its commutator with T is
[Lab,T]ij = δaiTbj - δbiTaj - δbjTia + δajTib
If a,b,i,j are all different, then this expression is zero. But let's try ab = 12 and ij = 13 for definiteness. Then it equals T23. Thus, for number of dimensions >= 3, all off-diagonal T is zero.
Let's turn to ab = 12 and ij = 11. We get T21 + T12 = 0, or Tij ~ εij, the antisymmetric symbol.
Turning to ab = 12 and ij = 12, we get T22 - T11 = 0
We thus find two possible invariants: T ~ δ for all numbers of dimensions and also T ~ ε for two dimensions.
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Alternately, we can contract the commutator on b and j, giving δaiTr(T) - Tai - (n-1)*Tia for n dimensions.
Adding (ai) and (ia) gives 2*δaiTr(T) - n*(Tai + Tia)
Thus, the symmetric part of T is proportional to δ.
Subtracting instead gives (n-2)*(Tia - Tai)
Thus, the antisymmetric part of T vanishes, except for 2 dimensions, where it is proportional to ε.